ACS Publications. Most Trusted. Most Cited. Most Read

OR SEARCH CITATIONS

My Activity
Publications
CONTENT TYPES

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Phys. Chem. A 2000, 104, 24, 5660-5694
RETURN TO ISSUEPREVFeature ArticleNEXT

Femtochemistry:  Atomic-Scale Dynamics of the Chemical Bond†

View Author Information
Arthur Amos Noyes Laboratory of Chemical Physics, Laboratory for Molecular Sciences, California Institute of Technology, Pasadena, California 91125
Cite this: J. Phys. Chem. A 2000, 104, 24, 5660–5694
Publication Date (Web):May 31, 2000
https://doi.org/10.1021/jp001460h
Copyright © 2000 American Chemical Society
Request reuse permissions

    Article Views

    22953

    Altmetric

    -

    Citations

    1443
    LEARN ABOUT THESE METRICS
    Other access options
    Get e-Alerts
    SUBJECTS:

    Abstract

    This anthology, which is adapted from the Nobel Lecture, gives an overview of the field of Femtochemistry from a personal perspective, encompassing our research at Caltech and focusing on the evolution of techniques, concepts, and new discoveries. In developing femtochemistrythe study of molecular motions in the ephemeral transition states of physical, chemical, and biological changeswe have harnessed the powerful concept of molecular coherence and developed ultrafast-laser techniques for observing these motions. Femtosecond resolution (1 fs = 10-15 s) is the ultimate achievement for studies of the dynamics of the chemical bond at the atomic level. On this time scale, matter wave packets (particle-type) can be created and their coherent evolution as a single-molecule trajectory can be observed. The field began with simple systems of a few atoms and has reached the realm of the very complex in isolated, mesoscopic, and condensed phases and in biological systems such as proteins and DNA. It also offers new possibilities for the control of reactivity and for structural femtochemistry and femtobiology.

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. You can change your affiliated institution below.

    †

     Adapted from the Nobel Lecture. All figures are used with the permission of the author.

    Cited By

    This article is cited by 1443 publications.

    1. Shintaro Saeki, Daisuke Kawaguchi, Yuta Tsuji, Satoru Yamamoto, Kazunari Yoshizawa, Keiji Tanaka. Electronic Interaction of Epoxy Resin with Copper at the Adhered Interface. Langmuir 2024, 40 (18) , 9725-9731. https://doi.org/10.1021/acs.langmuir.4c00711
    2. Marcos Dantus. Tracking Molecular Fragmentation in Electron–Ionization Mass Spectrometry with Ultrafast Time Resolution. Accounts of Chemical Research 2024, 57 (6) , 845-854. https://doi.org/10.1021/acs.accounts.3c00713
    3. Lijie Wang, Razan Nughays, Thomas C. Rossi, Malte Oppermann, Wojciech Ogieglo, Tieyuan Bian, Chun-Hua Shih, Tzung-Fang Guo, Ingo Pinnau, Jun Yin, Osman M. Bakr, Omar F. Mohammed, Majed Chergui. Disentangling Thermal from Electronic Contributions in the Spectral Response of Photoexcited Perovskite Materials. Journal of the American Chemical Society 2024, 146 (8) , 5393-5401. https://doi.org/10.1021/jacs.3c12832
    4. László Biró, András Csehi. Attosecond Probing of Nuclear Vibrations in the D2+ and HeH+ Molecular Ions. The Journal of Physical Chemistry A 2024, 128 (5) , 858-867. https://doi.org/10.1021/acs.jpca.3c07031
    5. Wen-Quan Jing, Zhao-Peng Sun, Song-Feng Zhao, Chuan-Cun Shu. Unveiling Coherent Control of Halomethane Dissociation Induced by a Single Strong Ultraviolet Pulse. The Journal of Physical Chemistry Letters 2023, 14 (50) , 11305-11312. https://doi.org/10.1021/acs.jpclett.3c03143
    6. Dexia Zhou, Fang Zhang, Baihui Wang, Jiman He, Yimin Bai, Hongtao Bian. Anion Recognition in Solution: Insights from Thermodynamics and Ultrafast Structural Dynamics. The Journal of Physical Chemistry Letters 2023, 14 (49) , 11183-11189. https://doi.org/10.1021/acs.jpclett.3c02996
    7. Adam Šrut, Vera Krewald. Vibrational Coherences of the Photoinduced Mixed-Valent Creutz–Taube Ion Revealed by Excited State Dynamics. The Journal of Physical Chemistry A 2023, 127 (47) , 9911-9920. https://doi.org/10.1021/acs.jpca.3c04415
    8. Lena Bäuml, Florian Rott, Thomas Schnappinger, Regina de Vivie-Riedle. Following the Nonadiabatic Ultrafast Dynamics of Uracil via Simulated X-ray Absorption Spectra. The Journal of Physical Chemistry A 2023, 127 (46) , 9787-9796. https://doi.org/10.1021/acs.jpca.3c06509
    9. Jan Helbing, Peter Hamm. Versatile Femtosecond Laser Synchronization for Multiple-Timescale Transient Infrared Spectroscopy. The Journal of Physical Chemistry A 2023, 127 (30) , 6347-6356. https://doi.org/10.1021/acs.jpca.3c03526
    10. Paul M. Donaldson, Greg M. Greetham, Chris T. Middleton, Bradley M. Luther, Martin T. Zanni, Peter Hamm, Amber T. Krummel. Breaking Barriers in Ultrafast Spectroscopy and Imaging Using 100 kHz Amplified Yb-Laser Systems. Accounts of Chemical Research 2023, 56 (15) , 2062-2071. https://doi.org/10.1021/acs.accounts.3c00152
    11. Andrea Baldi, Sven H. C. Askes. Pulsed Photothermal Heterogeneous Catalysis. ACS Catalysis 2023, 13 (5) , 3419-3432. https://doi.org/10.1021/acscatal.2c05435
    12. Jino George, Jaibir Singh. Polaritonic Chemistry: Band-Selective Control of Chemical Reactions by Vibrational Strong Coupling. ACS Catalysis 2023, 13 (4) , 2631-2636. https://doi.org/10.1021/acscatal.2c05201
    13. Roman Bause, Arthur Christianen, Andreas Schindewolf, Immanuel Bloch, Xin-Yu Luo. Ultracold Sticky Collisions: Theoretical and Experimental Status. The Journal of Physical Chemistry A 2023, 127 (3) , 729-741. https://doi.org/10.1021/acs.jpca.2c08095
    14. Wataru Yajima, Yusuke Arashida, Ryota Nishimori, Yuga Emoto, Yuki Yamamoto, Kohei Kawasaki, Yuri Saida, Samuel Jeong, Keishi Akada, Kou Takubo, Hidemi Shigekawa, Jun-ichi Fujita, Shin-ya Koshihara, Shoji Yoshida, Masaki Hada. Streaking of a Picosecond Electron Pulse with a Weak Terahertz Pulse. ACS Photonics 2023, 10 (1) , 116-124. https://doi.org/10.1021/acsphotonics.2c01304
    15. Maxim F. Gelin, Lipeng Chen, Wolfgang Domcke. Equation-of-Motion Methods for the Calculation of Femtosecond Time-Resolved 4-Wave-Mixing and N-Wave-Mixing Signals. Chemical Reviews 2022, 122 (24) , 17339-17396. https://doi.org/10.1021/acs.chemrev.2c00329
    16. Natsumi Fukaya, Soichiro Ogi, Hikaru Sotome, Kazuhiro J. Fujimoto, Takeshi Yanai, Nils Bäumer, Gustavo Fernández, Hiroshi Miyasaka, Shigehiro Yamaguchi. Impact of Hydrophobic/Hydrophilic Balance on Aggregation Pathways, Morphologies, and Excited-State Dynamics of Amphiphilic Diketopyrrolopyrrole Dyes in Aqueous Media. Journal of the American Chemical Society 2022, 144 (49) , 22479-22492. https://doi.org/10.1021/jacs.2c07299
    17. Haiwang Yong, Shichao Sun, Bing Gu, Shaul Mukamel. Attosecond Charge Migration in Molecules Imaged by Combined X-ray and Electron Diffraction. Journal of the American Chemical Society 2022, 144 (45) , 20710-20716. https://doi.org/10.1021/jacs.2c07997
    18. Yuri Saida, Ryo Shikata, Kaito En-ya, Satoshi Ohmura, Yuta Nishina, Masaki Hada. Development of a Multitimescale Time-Resolved Electron Diffraction Setup: Photoinduced Dynamics of Oxygen Radicals on Graphene Oxide. The Journal of Physical Chemistry A 2022, 126 (36) , 6301-6308. https://doi.org/10.1021/acs.jpca.2c04075
    19. Morgane Vacher, Alexie Boyer, Vincent Loriot, Franck Lépine, Saikat Nandi. Few-Femtosecond Isotope Effect in Polyatomic Molecules Ionized by Extreme Ultraviolet Attosecond Pulse Trains. The Journal of Physical Chemistry A 2022, 126 (34) , 5692-5701. https://doi.org/10.1021/acs.jpca.2c03487
    20. Yang Luo, Alberto Martin-Jimenez, Rico Gutzler, Manish Garg, Klaus Kern. Ultrashort Pulse Excited Tip-Enhanced Raman Spectroscopy in Molecules. Nano Letters 2022, 22 (13) , 5100-5106. https://doi.org/10.1021/acs.nanolett.2c00485
    21. Somnath Biswas, JunWoo Kim, Xinzi Zhang, Gregory D. Scholes. Coherent Two-Dimensional and Broadband Electronic Spectroscopies. Chemical Reviews 2022, 122 (3) , 4257-4321. https://doi.org/10.1021/acs.chemrev.1c00623
    22. Andrew S. Durden, Benjamin G. Levine. Floquet Time-Dependent Configuration Interaction for Modeling Ultrafast Electron Dynamics. Journal of Chemical Theory and Computation 2022, 18 (2) , 795-806. https://doi.org/10.1021/acs.jctc.1c01009
    23. Prashant Kumar, Aditya Dey, Jerome Roques, Loic Assaud, Sylvain Franger, Prakash Parida, Vasudevanpillai Biju. Photoexfoliation Synthesis of 2D Materials. ACS Materials Letters 2022, 4 (2) , 263-270. https://doi.org/10.1021/acsmaterialslett.1c00651
    24. Dexia Zhou, Boxu Zhao, Yimin Bai, Somnath Mukherjee, Jing Liu, Hongtao Bian, Yu Fang. Exploring the Structure and Complexation Dynamics of Azide Anion Recognition by Calix[4]pyrroles in Solution. The Journal of Physical Chemistry Letters 2022, 13 (2) , 669-675. https://doi.org/10.1021/acs.jpclett.1c03962
    25. Safayet Ahmed, Junpeng Qiao, Ping Kwong Cheng, Ahmed Mortuza Saleque, Md. Nahian Al Subri Ivan, Tawsif Ibne Alam, Yuen Hong Tsang. Two-Dimensional Gallium Sulfide as a Novel Saturable Absorber for Broadband Ultrafast Photonics Applications. ACS Applied Materials & Interfaces 2021, 13 (51) , 61518-61527. https://doi.org/10.1021/acsami.1c18155
    26. Dexia Zhou, Miaomiao Zhang, Yinhua Ma, Somnath Mukherjee, Jing Liu, Hongtao Bian. Cationic Effects on the Structural Dynamics of the Metal Ion–Crown Ether Complexes Investigated by Ultrafast Infrared Spectroscopy. The Journal of Physical Chemistry B 2021, 125 (46) , 12797-12805. https://doi.org/10.1021/acs.jpcb.1c07902
    27. Edward G. Hohenstein, Jimmy K. Yu, Christoph Bannwarth, Nanna Holmgaard List, Alexander C. Paul, Sarai D. Folkestad, Henrik Koch, Todd J. Martínez. Predictions of Pre-edge Features in Time-Resolved Near-Edge X-ray Absorption Fine Structure Spectroscopy from Hole–Hole Tamm–Dancoff-Approximated Density Functional Theory. Journal of Chemical Theory and Computation 2021, 17 (11) , 7120-7133. https://doi.org/10.1021/acs.jctc.1c00478
    28. Theis I. Solling. Nonstatistical Photoinduced Processes in Gaseous Organic Molecules. ACS Omega 2021, 6 (44) , 29325-29344. https://doi.org/10.1021/acsomega.1c04035
    29. Hrvoje Petek Yanan Dai Atreyie Ghosh Andi Li Zhikang Zhou Marcel Reutzel Sena Yang Chen-Bin Huang . Light Matter. , 153-171. https://doi.org/10.1021/bk-2021-1398.ch008
    30. Giovanni Batignani, Carlotta Sansone, Carino Ferrante, Giuseppe Fumero, Shaul Mukamel, Tullio Scopigno. Excited-State Energy Surfaces in Molecules Revealed by Impulsive Stimulated Raman Excitation Profiles. The Journal of Physical Chemistry Letters 2021, 12 (38) , 9239-9247. https://doi.org/10.1021/acs.jpclett.1c02209
    31. Meera Madhu, Remya Ramakrishnan, Vishnu Vijay, Mahesh Hariharan. Free Charge Carriers in Homo-Sorted π-Stacks of Donor–Acceptor Conjugates. Chemical Reviews 2021, 121 (13) , 8234-8284. https://doi.org/10.1021/acs.chemrev.1c00078
    32. Na Kong, Jing Guo, Shuai Chang, Jie Pan, Jianmei Wang, Jianghao Zhou, Jing Liu, Hong Zhou, Frederick M. Pfeffer, Jingquan Liu, Colin J. Barrow, Jin He, Wenrong Yang. Direct Observation of Amide Bond Formation in a Plasmonic Nanocavity Triggered by Single Nanoparticle Collisions. Journal of the American Chemical Society 2021, 143 (26) , 9781-9790. https://doi.org/10.1021/jacs.1c02426
    33. Brankica Jankovic, Olga Bozovic, Peter Hamm. Intrinsic Dynamics of Protein–Peptide Unbinding. Biochemistry 2021, 60 (22) , 1755-1763. https://doi.org/10.1021/acs.biochem.1c00262
    34. Longxing Zhou, Yang Liu, Tian Sun, Hang Yin, Yiwen Zhao, Hang Lv, Haifeng Xu. Strong Field Ionization-Photofragmentation on Ultrafast Evolution of Electronic States of Toluene Cations. The Journal of Physical Chemistry A 2021, 125 (10) , 2095-2100. https://doi.org/10.1021/acs.jpca.0c11547
    35. César Barrales-Martínez, Jorge I. Martínez-Araya, Pablo Jaque. 1,3-Dipolar Cycloadditions by a Unified Perspective Based on Conceptual and Thermodynamics Models of Chemical Reactivity. The Journal of Physical Chemistry A 2021, 125 (3) , 801-815. https://doi.org/10.1021/acs.jpca.0c10013
    36. Marcelo G. Vivas, Cristina A. Barboza, Jose C. Germino, Ruben D. Fonseca, Daniel L. Silva, Pedro A. M. Vazquez, Teresa D. Z. Atvars, Cleber R. Mendonça, Leonardo De Boni. Molecular Structure–Optical Property Relationship of Salicylidene Derivatives: A Study on the First-Order Hyperpolarizability. The Journal of Physical Chemistry A 2021, 125 (1) , 99-105. https://doi.org/10.1021/acs.jpca.0c08530
    37. Adam A. Wallace, Yerbolat Dauletyarov, Andrei Sanov. Diradical Interactions in Ring-Open Isoxazole. The Journal of Physical Chemistry A 2021, 125 (1) , 317-326. https://doi.org/10.1021/acs.jpca.0c10102
    38. Pascale Changenet, Thomas Gustavsson, Isabelle Lampre. Introduction to Femtochemistry: Excited-State Proton Transfer from Pyranine to Water Studied by Femtosecond Transient Absorption. Journal of Chemical Education 2020, 97 (12) , 4482-4489. https://doi.org/10.1021/acs.jchemed.0c01056
    39. Ruidan Zhu, Jiading Zou, Zhuan Wang, Hailong Chen, Yuxiang Weng. Electronic State-Resolved Multimode-Coupled Vibrational Wavepackets in Oxazine 720 by Two-Dimensional Electronic Spectroscopy. The Journal of Physical Chemistry A 2020, 124 (45) , 9333-9342. https://doi.org/10.1021/acs.jpca.0c06559
    40. Chong Chiat Lim, San Kiong Lai. Enantiomeric Transitions in the Chiral Cluster Au15 Studied by a Reaction Coordinate Deduced from Molecular Dynamics Simulations. The Journal of Physical Chemistry A 2020, 124 (42) , 8679-8691. https://doi.org/10.1021/acs.jpca.0c05099
    41. Giovanni Batignani, Carino Ferrante, Tullio Scopigno. Accessing Excited State Molecular Vibrations by Femtosecond Stimulated Raman Spectroscopy. The Journal of Physical Chemistry Letters 2020, 11 (18) , 7805-7813. https://doi.org/10.1021/acs.jpclett.0c01971
    42. Chengbo Li, Aili Wang, Xiaoyu Deng, Shurong Wang, Yuan Yuan, Liming Ding, Feng Hao. Insights into Ultrafast Carrier Dynamics in Perovskite Thin Films and Solar Cells. ACS Photonics 2020, 7 (8) , 1893-1907. https://doi.org/10.1021/acsphotonics.0c00677
    43. Diana Yepes, Julen Munarriz, Daniel l’Anson, Julia Contreras-Garcia, Pablo Jaque. Real-Space Approach to the Reaction Force: Understanding the Origin of Synchronicity/Nonsynchronicity in Multibond Chemical Reactions. The Journal of Physical Chemistry A 2020, 124 (10) , 1959-1972. https://doi.org/10.1021/acs.jpca.9b10508
    44. Tammie R. Nelson, Alexander J. White, Josiah A. Bjorgaard, Andrew E. Sifain, Yu Zhang, Benjamin Nebgen, Sebastian Fernandez-Alberti, Dmitry Mozyrsky, Adrian E. Roitberg, Sergei Tretiak. Non-adiabatic Excited-State Molecular Dynamics: Theory and Applications for Modeling Photophysics in Extended Molecular Materials. Chemical Reviews 2020, 120 (4) , 2215-2287. https://doi.org/10.1021/acs.chemrev.9b00447
    45. Guillermo González-Rubio, Thais Milagres de Oliveira, Wiebke Albrecht, Pablo Díaz-Núñez, Juan Carlos Castro-Palacio, Alejandro Prada, Rafael I. González, Leonardo Scarabelli, Luis Bañares, Antonio Rivera, Luis M. Liz-Marzán, Ovidio Peña-Rodríguez, Sara Bals, Andrés Guerrero-Martínez. Formation of Hollow Gold Nanocrystals by Nanosecond Laser Irradiation. The Journal of Physical Chemistry Letters 2020, 11 (3) , 670-677. https://doi.org/10.1021/acs.jpclett.9b03574
    46. Yusuke Yoneda, Hikaru Sotome, Reshma Mathew, Yapamanu Adithya Lakshmanna, Hiroshi Miyasaka. Non-condon Effect on Ultrafast Excited-State Intramolecular Proton Transfer. The Journal of Physical Chemistry A 2020, 124 (2) , 265-271. https://doi.org/10.1021/acs.jpca.9b09085
    47. Margherita Maiuri, Marco Garavelli, Giulio Cerullo. Ultrafast Spectroscopy: State of the Art and Open Challenges. Journal of the American Chemical Society 2020, 142 (1) , 3-15. https://doi.org/10.1021/jacs.9b10533
    48. Longxing Zhou, Yang Liu, Tian Sun, Shuang Feng, Hang Lv, Haifeng Xu. Ultrafast Evolution of B2E2g - X2E1g Conical Intersection of Benzene Cations by Strong Field Ionization-Photo Fragmentation. The Journal of Physical Chemistry A 2019, 123 (39) , 8365-8369. https://doi.org/10.1021/acs.jpca.9b07044
    49. Xiaojin Guo, Zhenyu Liu, Yunhan Xiao, Xiang Xu, Xiaoyong Xue, Qingya Liu, Xiquan Li. Simulations on Pyrolysis of Different Coals by the Boltzmann–Monte Carlo Percolation (BMCP) Model. Energy & Fuels 2019, 33 (4) , 3144-3154. https://doi.org/10.1021/acs.energyfuels.9b00261
    50. Meisam Farzalipour Tabriz, Natali Çizmeciyan, Özgür Birer, Ersin Yurtsever. Energy Landscapes in Photochemical Dissociation of Small Peroxides. The Journal of Physical Chemistry A 2019, 123 (7) , 1353-1362. https://doi.org/10.1021/acs.jpca.8b08666
    51. Kai-Jun Yuan, André D. Bandrauk. Ultrafast X-ray Photoelectron Imaging of Attosecond Electron Dynamics in Molecular Coherent Excitation. The Journal of Physical Chemistry A 2019, 123 (7) , 1328-1336. https://doi.org/10.1021/acs.jpca.8b12313
    52. Zhengrong Wei, Li Tian, Jialin Li, Yunpeng Lu, Minghui Yang, Zhi-Heng Loh. Tracking Ultrafast Bond Dissociation Dynamics at 0.1 Å Resolution by Femtosecond Extreme Ultraviolet Absorption Spectroscopy. The Journal of Physical Chemistry Letters 2018, 9 (19) , 5742-5747. https://doi.org/10.1021/acs.jpclett.8b02547
    53. Fengzi Ling, Yanmei Wang, Shuai Li, Jie Wei, Ying Tang, Bing Zhang. Imaging Reversible and Irreversible Structural Evolution in Photoexcited 2,4-Difluoroaniline. The Journal of Physical Chemistry Letters 2018, 9 (18) , 5468-5473. https://doi.org/10.1021/acs.jpclett.8b01841
    54. Wei-Tao Peng, B. Scott Fales, Benjamin G. Levine. Simulating Electron Dynamics of Complex Molecules with Time-Dependent Complete Active Space Configuration Interaction. Journal of Chemical Theory and Computation 2018, 14 (8) , 4129-4138. https://doi.org/10.1021/acs.jctc.8b00381
    55. Rachel Crespo-Otero, Mario Barbatti. Recent Advances and Perspectives on Nonadiabatic Mixed Quantum–Classical Dynamics. Chemical Reviews 2018, 118 (15) , 7026-7068. https://doi.org/10.1021/acs.chemrev.7b00577
    56. Thomas J. Penfold, Etienne Gindensperger, Chantal Daniel, Christel M. Marian. Spin-Vibronic Mechanism for Intersystem Crossing. Chemical Reviews 2018, 118 (15) , 6975-7025. https://doi.org/10.1021/acs.chemrev.7b00617
    57. Conor D. Rankine, João Pedro F. Nunes, Tomas W. B. Lock Feixas, Stuart Young, Derek A. Wann. Structure of 4-(Dimethylamino)benzonitrile Using Gas Electron Diffraction: A New Lease of Life for the Only Gas Electron Diffractometer in the U.K. . The Journal of Physical Chemistry A 2018, 122 (25) , 5656-5665. https://doi.org/10.1021/acs.jpca.8b03613
    58. Patrick Figliozzi, Curtis W. Peterson, Stuart A. Rice, Norbert F. Scherer. Direct Visualization of Barrier Crossing Dynamics in a Driven Optical Matter System. ACS Nano 2018, 12 (6) , 5168-5175. https://doi.org/10.1021/acsnano.8b02012
    59. Pooria Hosseini, Alexey Ermolov, Francesco Tani, David Novoa, Philip St.J. Russell. UV Soliton Dynamics and Raman-Enhanced Supercontinuum Generation in Photonic Crystal Fiber. ACS Photonics 2018, 5 (6) , 2426-2430. https://doi.org/10.1021/acsphotonics.8b00197
    60. Nicholas A. Miller, Aniruddha Deb, Roberto Alonso-Mori, James M. Glownia, Laura M. Kiefer, Arkaprabha Konar, Lindsay B. Michocki, Marcin Sikorski, Danielle L. Sofferman, Sanghoon Song, Megan J. Toda, Theodore E. Wiley, Diling Zhu, Pawel M. Kozlowski, Kevin J. Kubarych, James E. Penner-Hahn, Roseanne J. Sension. Ultrafast X-ray Absorption Near Edge Structure Reveals Ballistic Excited State Structural Dynamics. The Journal of Physical Chemistry A 2018, 122 (22) , 4963-4971. https://doi.org/10.1021/acs.jpca.8b04223
    61. Sabrina Simoncelli, Yi Li, Emiliano Cortés, Stefan A. Maier. Nanoscale Control of Molecular Self-Assembly Induced by Plasmonic Hot-Electron Dynamics. ACS Nano 2018, 12 (3) , 2184-2192. https://doi.org/10.1021/acsnano.7b08563
    62. Kai-Jun Yuan and André D. Bandrauk . Time-Resolved Photoelectron Imaging of Molecular Coherent Excitation and Charge Migration by Ultrashort Laser Pulses. The Journal of Physical Chemistry A 2018, 122 (8) , 2241-2249. https://doi.org/10.1021/acs.jpca.7b11669
    63. Nilangshu Mandal and Ayan Datta . Dynamical Effects along the Bifurcation Pathway Control Semibullvalene Formation in Deazetization Reactions. The Journal of Physical Chemistry B 2018, 122 (3) , 1239-1244. https://doi.org/10.1021/acs.jpcb.7b09533
    64. Zhengrong Wei, Jialin Li, Soo Teck See, and Zhi-Heng Loh . Spin–Orbit State-Selective C–I Dissociation Dynamics of the CH3I+ X̃ Electronic State Induced by Intense Few-Cycle Laser Fields. The Journal of Physical Chemistry Letters 2017, 8 (24) , 6067-6072. https://doi.org/10.1021/acs.jpclett.7b03022
    65. Noemí Alarcos, Boiko Cohen, Marcin Ziółek, and Abderrazzak Douhal . Photochemistry and Photophysics in Silica-Based Materials: Ultrafast and Single Molecule Spectroscopy Observation. Chemical Reviews 2017, 117 (22) , 13639-13720. https://doi.org/10.1021/acs.chemrev.7b00422
    66. Kristin Munkerup, Dmitri Romanov, Timothy Bohinski, Anne B. Stephansen, Robert J Levis, and Theis I. Sølling . Conserving Coherence and Storing Energy during Internal Conversion: Photoinduced Dynamics of cis- and trans-Azobenzene Radical Cations. The Journal of Physical Chemistry A 2017, 121 (45) , 8642-8651. https://doi.org/10.1021/acs.jpca.7b09185
    67. Gao-Lei Hou, Xue-Bin Wang, Anne B. McCoy, and Weston Thatcher Borden . Experimental and Theoretical Studies of the F• + H–F Transition-State Region by Photodetachment of [F–H–F]−. The Journal of Physical Chemistry A 2017, 121 (41) , 7895-7902. https://doi.org/10.1021/acs.jpca.7b07682
    68. Markus Kowalewski, Benjamin P. Fingerhut, Konstantin E. Dorfman, Kochise Bennett, and Shaul Mukamel . Simulating Coherent Multidimensional Spectroscopy of Nonadiabatic Molecular Processes: From the Infrared to the X-ray Regime. Chemical Reviews 2017, 117 (19) , 12165-12226. https://doi.org/10.1021/acs.chemrev.7b00081
    69. Gerard Lligadas, Silvia Grama, and Virgil Percec . Single-Electron Transfer Living Radical Polymerization Platform to Practice, Develop, and Invent. Biomacromolecules 2017, 18 (10) , 2981-3008. https://doi.org/10.1021/acs.biomac.7b01131
    70. Maciej Dąbrowski, Yanan Dai, and Hrvoje Petek . Ultrafast Microscopy: Imaging Light with Photoelectrons on the Nano–Femto Scale. The Journal of Physical Chemistry Letters 2017, 8 (18) , 4446-4455. https://doi.org/10.1021/acs.jpclett.7b00904
    71. Michel Broquier, Satchin Soorkia, Gustavo Pino, Claude Dedonder-Lardeux, Christophe Jouvet, and Gilles Grégoire . Excited State Dynamics of Cold Protonated Cytosine Tautomers: Characterization of Charge Transfer, Intersystem Crossing, and Internal Conversion Processes. The Journal of Physical Chemistry A 2017, 121 (34) , 6429-6439. https://doi.org/10.1021/acs.jpca.7b06423
    72. Mauro Nisoli, Piero Decleva, Francesca Calegari, Alicia Palacios, and Fernando Martín . Attosecond Electron Dynamics in Molecules. Chemical Reviews 2017, 117 (16) , 10760-10825. https://doi.org/10.1021/acs.chemrev.6b00453
    73. Majed Chergui and Eric Collet . Photoinduced Structural Dynamics of Molecular Systems Mapped by Time-Resolved X-ray Methods. Chemical Reviews 2017, 117 (16) , 11025-11065. https://doi.org/10.1021/acs.chemrev.6b00831
    74. Kai-Jun Yuan, Chuan-Cun Shu, Daoyi Dong, and André D. Bandrauk . Attosecond Dynamics of Molecular Electronic Ring Currents. The Journal of Physical Chemistry Letters 2017, 8 (10) , 2229-2235. https://doi.org/10.1021/acs.jpclett.7b00877
    75. Yoichi Kobayashi, Hajime Okajima, Hikaru Sotome, Takeshi Yanai, Katsuya Mutoh, Yusuke Yoneda, Yasuteru Shigeta, Akira Sakamoto, Hiroshi Miyasaka, and Jiro Abe . Direct Observation of the Ultrafast Evolution of Open-Shell Biradical in Photochromic Radical Dimer. Journal of the American Chemical Society 2017, 139 (18) , 6382-6389. https://doi.org/10.1021/jacs.7b01598
    76. Eric A. Pozzi, Guillaume Goubert, Naihao Chiang, Nan Jiang, Craig T. Chapman, Michael O. McAnally, Anne-Isabelle Henry, Tamar Seideman, George C. Schatz, Mark C. Hersam, and Richard P. Van Duyne . Ultrahigh-Vacuum Tip-Enhanced Raman Spectroscopy. Chemical Reviews 2017, 117 (7) , 4961-4982. https://doi.org/10.1021/acs.chemrev.6b00343
    77. Lorenzo Monacelli, Giovanni Batignani, Giuseppe Fumero, Carino Ferrante, Shaul Mukamel, and Tullio Scopigno . Manipulating Impulsive Stimulated Raman Spectroscopy with a Chirped Probe Pulse. The Journal of Physical Chemistry Letters 2017, 8 (5) , 966-974. https://doi.org/10.1021/acs.jpclett.6b03027
    78. Chuan-Cun Shu, Kai-Jun Yuan, Daoyi Dong, Ian R. Petersen, and Andre D. Bandrauk . Identifying Strong-Field Effects in Indirect Photofragmentation Reactions. The Journal of Physical Chemistry Letters 2017, 8 (1) , 1-6. https://doi.org/10.1021/acs.jpclett.6b02613
    79. Robson da Silva Oliboni, Graziele Bortolini, Alberto Torres, and Luis G. C. Rego . A Nonadiabatic Excited State Molecular Mechanics/Extended Hückel Ehrenfest Method. The Journal of Physical Chemistry C 2016, 120 (48) , 27688-27698. https://doi.org/10.1021/acs.jpcc.6b09606
    80. Alessio Petrone, David B. Lingerfelt, David B. Williams-Young, and Xiaosong Li . Ab Initio Transient Vibrational Spectral Analysis. The Journal of Physical Chemistry Letters 2016, 7 (22) , 4501-4508. https://doi.org/10.1021/acs.jpclett.6b02292
    81. Eric A. Pozzi, Natalie L. Gruenke, Naihao Chiang, Dmitry V. Zhdanov, Nan Jiang, Tamar Seideman, George C. Schatz, Mark C. Hersam, and Richard P. Van Duyne . Operational Regimes in Picosecond and Femtosecond Pulse-Excited Ultrahigh Vacuum SERS. The Journal of Physical Chemistry Letters 2016, 7 (15) , 2971-2976. https://doi.org/10.1021/acs.jpclett.6b01151
    82. James W. Snyder, Jr., Basile F. E. Curchod, and Todd J. Martínez . GPU-Accelerated State-Averaged Complete Active Space Self-Consistent Field Interfaced with Ab Initio Multiple Spawning Unravels the Photodynamics of Provitamin D3. The Journal of Physical Chemistry Letters 2016, 7 (13) , 2444-2449. https://doi.org/10.1021/acs.jpclett.6b00970
    83. Xiangmeng Kong, Andreas Markmann, and Victor S. Batista . Time-Sliced Thawed Gaussian Propagation Method for Simulations of Quantum Dynamics. The Journal of Physical Chemistry A 2016, 120 (19) , 3260-3269. https://doi.org/10.1021/acs.jpca.5b12192
    84. Triet S. Nguyen, Joong Hoon Koh, Susan Lefelhocz, and John Parkhill . Black-Box, Real-Time Simulations of Transient Absorption Spectroscopy. The Journal of Physical Chemistry Letters 2016, 7 (8) , 1590-1595. https://doi.org/10.1021/acs.jpclett.6b00421
    85. Guillermo González-Rubio, Andrés Guerrero-Martínez, and Luis M. Liz-Marzán . Reshaping, Fragmentation, and Assembly of Gold Nanoparticles Assisted by Pulse Lasers. Accounts of Chemical Research 2016, 49 (4) , 678-686. https://doi.org/10.1021/acs.accounts.6b00041
    86. Daniele Fazzi, Mario Barbatti, and Walter Thiel . Unveiling the Role of Hot Charge-Transfer States in Molecular Aggregates via Nonadiabatic Dynamics. Journal of the American Chemical Society 2016, 138 (13) , 4502-4511. https://doi.org/10.1021/jacs.5b13210
    87. Jacob C. Dean, Daniel G. Oblinsky, Shahnawaz R. Rather, Gregory D. Scholes. Methylene Blue Exciton States Steer Nonradiative Relaxation: Ultrafast Spectroscopy of Methylene Blue Dimer. The Journal of Physical Chemistry B 2016, 120 (3) , 440-454. https://doi.org/10.1021/acs.jpcb.5b11847
    88. Alexander Weigel, Aleksandar Sebesta, and Philipp Kukura . Shaped and Feedback-Controlled Excitation of Single Molecules in the Weak-Field Limit. The Journal of Physical Chemistry Letters 2015, 6 (20) , 4032-4037. https://doi.org/10.1021/acs.jpclett.5b01748
    89. M. Liebel, C. Schnedermann, T. Wende, and P. Kukura . Principles and Applications of Broadband Impulsive Vibrational Spectroscopy. The Journal of Physical Chemistry A 2015, 119 (36) , 9506-9517. https://doi.org/10.1021/acs.jpca.5b05948
    90. Jacob C. Dean, Shahnawaz R. Rather, Daniel G. Oblinsky, Elsa Cassette, Chanelle C. Jumper, Gregory D. Scholes. Broadband Transient Absorption and Two-Dimensional Electronic Spectroscopy of Methylene Blue. The Journal of Physical Chemistry A 2015, 119 (34) , 9098-9108. https://doi.org/10.1021/acs.jpca.5b06126
    91. Dayne A. Plemmons, Pranav K. Suri, and David J. Flannigan . Probing Structural and Electronic Dynamics with Ultrafast Electron Microscopy. Chemistry of Materials 2015, 27 (9) , 3178-3192. https://doi.org/10.1021/acs.chemmater.5b00433
    92. Majed Chergui . Ultrafast Photophysics of Transition Metal Complexes. Accounts of Chemical Research 2015, 48 (3) , 801-808. https://doi.org/10.1021/ar500358q
    93. Chen Qiu and G. J. Blanchard . Evidence for Preferential Solvation in the Cyclohexane/n-Butanol Binary Solvent System. The Journal of Physical Chemistry B 2015, 119 (5) , 1986-1993. https://doi.org/10.1021/jp510964a
    94. Eric A. Pozzi, Matthew D. Sonntag, Nan Jiang, Naihao Chiang, Tamar Seideman, Mark C. Hersam, and Richard P. Van Duyne . Ultrahigh Vacuum Tip-Enhanced Raman Spectroscopy with Picosecond Excitation. The Journal of Physical Chemistry Letters 2014, 5 (15) , 2657-2661. https://doi.org/10.1021/jz501239z
    95. Huan Shen, Jianjun Chen, Linqiang Hua, and Bing Zhang . Photodissociation Dynamics of Allyl Chloride at 200 and 266 nm Studied by Time-Resolved Mass Spectrometry and Photoelectron Imaging. The Journal of Physical Chemistry A 2014, 118 (25) , 4444-4450. https://doi.org/10.1021/jp500495b
    96. Na Zhang, Shampa R. Samanta, Brad M. Rosen, and Virgil Percec . Single Electron Transfer in Radical Ion and Radical-Mediated Organic, Materials and Polymer Synthesis. Chemical Reviews 2014, 114 (11) , 5848-5958. https://doi.org/10.1021/cr400689s
    97. Scott D. McClure, Daniel B. Turner, Paul C. Arpin, Tihana Mirkovic, and Gregory D. Scholes . Coherent Oscillations in the PC577 Cryptophyte Antenna Occur in the Excited Electronic State. The Journal of Physical Chemistry B 2014, 118 (5) , 1296-1308. https://doi.org/10.1021/jp411924c
    98. Hrvoje Petek . Single-Molecule Femtochemistry: Molecular Imaging at the Space-Time Limit. ACS Nano 2014, 8 (1) , 5-13. https://doi.org/10.1021/nn4064538
    99. Sanghamitra Deb, Xinxin Cheng, and Peter M. Weber . Structural Dynamics and Charge Transfer in Electronically Excited N,N′-Dimethylpiperazine. The Journal of Physical Chemistry Letters 2013, 4 (16) , 2780-2784. https://doi.org/10.1021/jz401499q
    100. Sascha Fröbel, Sebastian Appel, Christian Ganter, and Peter Gilch . Extracting Picosecond Time Constants from Steady-State Spectroscopy: A Physical Chemistry Experiment. Journal of Chemical Education 2013, 90 (8) , 1082-1086. https://doi.org/10.1021/ed4001393
    Load more citations
    Download PDF

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    You’ve supercharged your research process with ACS and Mendeley!

    STEP 1:
    Click to create an ACS ID

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    MENDELEY PAIRING EXPIRED
    Your Mendeley pairing has expired. Please reconnect