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Interaction Between Graphene Oxide Nanoparticles and Quartz Sand

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School of Environmental Engineering, Technical University of Crete, 73100 Chania, Greece
*Fax: +30 28210 37847; e-mail: [email protected]
Cite this: Environ. Sci. Technol. 2015, 49, 22, 13413–13421
Publication Date (Web):October 14, 2015
https://doi.org/10.1021/acs.est.5b03496
Copyright © 2015 American Chemical Society

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    Abstract

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    In this study, the influence of pH, ionic strength (IS), and temperature on graphene oxide (GO) nanoparticles attachment onto quartz sand were investigated. Batch experiments were conducted at three controlled temperatures (4, 12, and 25 °C) in solutions with different pH values (pH 4, 7, and 10), and ionic strengths (IS = 1.4, 6.4, and 21.4 mM), under static and dynamic conditions. The surface properties of GO nanoparticles and quartz sand were evaluated by electrophoretic mobility measurements. Derjaguin–Landau–Verwey–Overbeek (DLVO) potential energy profiles were constructed for the experimental conditions, using measured zeta potentials. The experimental results showed that GO nanoparticles were very stable under the experimental conditions. Both temperature and pH did not play a significant role in the attachment of GO nanoparticles onto quartz sand. In contrast, IS was shown to influence attachment. The attachment of GO particles onto quartz sand increased significantly with increasing IS. The experimental data were fitted nicely with a Freundlich isotherm, and the attachment kinetics were satisfactorily described with a pseudo-second-order model, which implies that the quartz sand exhibited substantial surface heterogeneity and that GO retention was governed by chemisorption. Furthermore, thermodynamic analysis revealed that the attachment process was nonspontaneous and endothermic, which may be associated with structural changes of the sand surfaces due to chemisorption. Therefore, secondary minimum interaction may not be the dominant mechanism for GO attachment onto the quartz sand under the experimental conditions.

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.est.5b03496.

    • Details of DLVO theory, additional mathematical expressions of the pseudo-second-order kinetic model, transmission electron micrograph images of GO flakes, the effect of solution pH on the zeta potential of GO and quartz sand suspensions, the effect of ionic strength on the zeta potential of GO and quartz sand, the effect of sonication time on the size of GO aggregates, the effect of time on the size of GO aggregates, the GO aggregate size under different experimental conditions, a compilation of kinetic batch experimental conditions, comparison of the R2 values of the three isotherm models tested, and the amount of GO attached onto quartz sand in the various kinetic batch experiments can be found in the Supporting Information section (PDF)

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