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Low Ice Adhesion Surfaces Based on Flexible Fluorinated Polymers with a Polynorbornene Backbone
- Cuiping Zhou
Cuiping ZhouSchool of Chemistry and Chemical Engineering, and Shandong Key Laboratory of Fluorine Chemistry and Chemical Engineering Materials, University of Jinan, Jinan 250022, ChinaMore by Cuiping Zhou
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- Xuan Zhao
Xuan ZhaoSchool of Chemistry and Chemical Engineering, and Shandong Key Laboratory of Fluorine Chemistry and Chemical Engineering Materials, University of Jinan, Jinan 250022, ChinaMore by Xuan Zhao
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- Xiaoyun Zhao
Xiaoyun ZhaoSchool of Chemistry and Chemical Engineering, and Shandong Key Laboratory of Fluorine Chemistry and Chemical Engineering Materials, University of Jinan, Jinan 250022, ChinaMore by Xiaoyun Zhao
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- Hui Li*
Hui Li*Email: [email protected]School of Chemistry and Chemical Engineering, and Shandong Key Laboratory of Fluorine Chemistry and Chemical Engineering Materials, University of Jinan, Jinan 250022, ChinaMore by Hui Li
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- Shuxiang Zhang
Shuxiang ZhangSchool of Chemistry and Chemical Engineering, and Shandong Key Laboratory of Fluorine Chemistry and Chemical Engineering Materials, University of Jinan, Jinan 250022, ChinaMore by Shuxiang Zhang
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- Wei Feng
Wei FengState Key Laboratory of Fluorinated Functional Membranes Materials, Shandong Dongyue Polymer Material Co., Ltd., Zibo 255000, ChinaMore by Wei Feng
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- Yongming Zhang
Yongming ZhangState Key Laboratory of Fluorinated Functional Membranes Materials, Shandong Dongyue Polymer Material Co., Ltd., Zibo 255000, ChinaMore by Yongming Zhang
Abstract
Realizing icephobic surfaces with low ice adhesion and durability continues to be fascinating as well as challenging. Herein, a norbornene-based fluorinated polymer (NFP) with high flexibility and high tensile strength is designed and fabricated using a fluorinated side chain and a norbornene backbone, displaying low ice shear strength less than 20 kPa and excellent durability. Experimental and theoretical analyses show that the flexibility of the polymer chains and the synergistic macromolecular aggregation of the fluorinated side groups and the norbornene backbone play key roles in the excellent surface icephobic properties of the NFP films. Moreover, we also develop a facile approach to the design of durable icephobic slippery surfaces, which possess remarkable icephobic performance. This study not only sheds light on the relationship between the polymer molecular structure and surface icephobic properties but also provides a new avenue to conveniently realize anti-icing coatings.
Cited By
This article is cited by 11 publications.
- Guangzeng Luo, Zhilu Gao, Cuiping Zhou, Yintan Huang, Shuangshuang Hu, Yifan Hu, Chuanyong Zong, Lan Lei, Hui Li. Well-Tailored Norbornene-Based Fluorinated Copolymers toward Modulating Icephobicity and Mechanical Robustness. Langmuir 2024, Article ASAP.
- Zahra Azimi Dijvejin, Behrooz Khatir, Kevin Golovin. Suspended Kirigami Surfaces for Multifoulant Adhesion Reduction. ACS Applied Materials & Interfaces 2022, 14 (4) , 6221-6229. https://doi.org/10.1021/acsami.1c22344
- Zhiwei He, Muhammad Imran Jamil, Tong Li, Qinghua Zhang. Enhanced Surface Icephobicity on an Elastic Substrate. Langmuir 2022, 38 (1) , 18-35. https://doi.org/10.1021/acs.langmuir.1c02168
- Andrew P. Nowak, Adam F. Gross, Elena Sherman, April R. Rodriguez, Michael Ventuleth, Ashley M. Nelson, Sharon Guan, Michael Gervasoni, Jason Graetz. Dual Component Passive Icephobic Coatings with Micron-Scale Phase-Separated 3D Structures. ACS Applied Materials & Interfaces 2021, 13 (35) , 42005-42013. https://doi.org/10.1021/acsami.1c10838
- Halar Memon, Davide S. A. De Focatiis, Kwing-So Choi, Xianghui Hou. Toward Exceptional Icephobicity with Chionophile-Inspired Durable Biomimetic Coatings. ACS Applied Polymer Materials 2021, 3 (8) , 4184-4194. https://doi.org/10.1021/acsapm.1c00623
- Zhilu Gao, Xuan Zhao, Guangzeng Luo, Wen Yang, Wenqi Zhang, Hang Wang, Chuanyong Zong, Lan Lei, Hui Li. Anti-fouling amphiphilic surfaces from norbornene-based fluorinated copolymers with excellent mechanical properties. Progress in Organic Coatings 2024, 190 , 108361. https://doi.org/10.1016/j.porgcoat.2024.108361
- Dagui Wang, Jinglong Yang, Junchang Guo, Zhijuan Duan, Deihui Wang, Fan Xia, Fei Deng, Xu Deng. Liquid-like polymer lubricating surfaces: Mechanism and applications. Nano Research 2024, 17 (2) , 476-491. https://doi.org/10.1007/s12274-023-5843-3
- Andrés Nistal, Benjamín Sierra-Martín, Antonio Fernández-Barbero. On the Durability of Icephobic Coatings: A Review. Materials 2024, 17 (1) , 235. https://doi.org/10.3390/ma17010235
- Jian Chen, Xu Chen, Umair Azhar, Xiaoyu Yang, Chunhua Zhou, Mei Yan, Hui Li, Chuanyong Zong. Flexible and Photo-responsive superwetting surfaces based on porous materials coated with Mussel-Inspired Azo-Copolymer. Chemical Engineering Journal 2023, 466 , 143176. https://doi.org/10.1016/j.cej.2023.143176
- JiaNan Huang, DaWei Li, ZhiLong Peng, Bo Zhang, Yin Yao, ShaoHua Chen. A new method based on the shear lag model for accurate determination of ice adhesion shear strength on solid surface. Science China Technological Sciences 2023, 66 (4) , 987-997. https://doi.org/10.1007/s11431-022-2202-2
- Jian Kuang, Xiaowei An, Congshu Huang, Hongfei Chen, Chunyang Wei. Design and preparation of durable anti‐icing polysilazane coatings with abrasion and UV resistance. Journal of Applied Polymer Science 2023, 140 (5) https://doi.org/10.1002/app.53416