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Nanogold: A Quantitative Phase Map

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† CSIRO Materials Science & Engineering, Clayton, 3168, Australia
‡ Department of Materials, University of Oxford Parks Road, Oxford, OX1 3PH, U.K.
§ Kavli Institute of Nanoscience, Delft University of Technology Lorentzweg 1, 2628 CJ Delft, The Netherlands
⊥ Department of Geology and Geophysics, and Materials Science Program University of Wisconsin—Madison, Madison, Wisconsin 53706
* Address correspondence to [email protected]
Cite this: ACS Nano 2009, 3, 6, 1431–1436
Publication Date (Web):June 2, 2009
https://doi.org/10.1021/nn900220k
Copyright © 2009 American Chemical Society
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    Abstract

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    The development of the next generation of nanotechnologies requires precise control of the size, shape, and structure of individual components in a variety of chemical and engineering environments. This includes synthesis, storage, operational environments and, since these products will ultimately be discarded, their interaction with natural ecosystems. Much of the important information that determines these properties is contained within nanoscale phase diagrams, but quantitative phase maps that include surface effects and critical diameter (along with temperature and pressure) remain elusive. Here we present the first quantitative equilibrium phase map for gold nanoparticles together with experimental verification, based on relativistic ab initio thermodynamics and in situ high-resolution electron microscopy at elevated temperatures.

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