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10 citations found for Shan, G.

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In the title mol­ecule, C16H10F3NO, the N-bound phenyl ring is oriented nearly orthogonal to the quinolinyl ring in order to avoid steric clashes with the trifluoro­methyl substituent [dihedral angle 89.7 (1)°].

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In the title compound, C20H19N3O4S, a novel tubulin ligand active against human cancer, the dihedral angle between the pyridine ring and the carbazole ring system is 42.87 (10)°. In the crystal, the mol­ecules are held together by N—H...O and C—H...O hydrogen bonds into layers, which are assembled into a three-dimensional network via π–π stacking inter­actions between inversion-related pyridine rings, with centroid–centroid distances of 3.5101 (12) Å.

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The title complex, (C6H16N)2[Zn(H2O)6](C10H6O6S2)2, is formed by aggregation of one hexa­hydrated zinc(II) cation, two triethyl­aminium cations and two naphthalene-1,6-disulfonate dianions. The ZnII cation is six-coordinate and located at an inversion center. The coordination around the metal ion is octa­hedral, with tetra­gonal elongation.

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A multicom­ponent pharmaceutical salt formed by the iso­quinoline alkaloid berberine (BBR) and the nonsteroidal anti-inflammatory drug diclofenac (DIC) was discovered. Five solvates of the BBR–DIC salt were obtained and their crystal structures determined.

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In the title compound, C6H16N+·C2HCl2O2, the cation exhibits non-crystallographic C2 symmetry. In the crystal, the components are linked by N—H...O and C—H...O hydrogen bonds into chains propagating along [010].

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In the title compound, C10H10N2O3, the five-membered imidazolidine ring is planar, with an r.m.s. derivation of 0.0243 (1)Å. The dihedral angle between the imidazolidine ring and the phenyl ring is 78.83 (2)°. A centrosymmetric ring is formed by a pair of N—H...O hydrogen bonds, creating a dimer; C—H...O hydrogen bonds connect these dimers into a three-dimensional network.

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In the title structure, C25H24FN3O5, a strong intra­molecular O—H...O hydrogen bond is present between the carb­oxy group at the 3-position and the carbonyl group at the 4-position. In the crystal, mol­ecules are held together by weak C—H...O, C—H...F and π–π [centroid–centroid distance 3.6080 (8) Å] inter­actions. The 1,4-dihydro­quinoline ring and cyclo­propyl group are not in the same plane, making an inter­planar angle of 57.52 (8)°.

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Synchrotron radiation wide-angle X-ray diffraction and small-angle X-ray scattering techniques have been used to investigate and elucidate the formation conditions, mechanism and phase transition of an unusual homocrystalline polymorph in stereocomplexable polymers.

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The title compound [systematic name: 11β-hydr­oxy-24,25-ep­oxy-3,16-oxo-protost-13 (17)-en-23-yl acetate], C32H48O6, a protostane-type triterpenoid, was isolated from the Chinese herbal medicine alismatis rhizoma (the rhizome of Alisma orientalis Juzep). The mol­ecule contains four trans-fused rings, viz. three six-membered and one five-membered ring. Two of the six-membered rings have slightly distorted half-chair conformations, while the third exhibits a chair conformation. The five-membered ring is almost planar. An inter­molecular O—H...O hydrogen bond between the hydr­oxy and ep­oxy groups and intra- and intermolecular C—H...O hydrogen bonds are observed.

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The crystal structure of the ternary phase Gd6FeBi2 is established from single-crystal X-ray diffraction data and the structural details are used to understand its high magnetic-ordering temperature. The combined structural analysis and first-principles electronic structure calculations suggest the enhanced magnetic-exchange inter­actions to be due to the significant Gd 5d–Fe 3d hybridization. Strong Gd—Gd bonding is present in this Gd-rich material, but the Gd—Bi inter­actions are shown to be weak.

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