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  PET extrusion

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Author Topic:   PET extrusion
esskayplastics
Member

Posts: 1
From:nagpur,maharashtra,india
Registered: Sep 2004

posted September 25, 2004 12:09 AM     Click Here to See the Profile for esskayplastics   Click Here to Email esskayplastics     Edit/Delete Message   Reply w/Quote
I have a single screw extruder being used to recycle PP,HDPE,LDPE waste.I need to recycle PET bottle waste to granules.What changes need to be made to make the same screw suitable for this??
The l/d ratio of this 65 mm screw is 30:1.
Detailed information about PET extrusion parameters would be welcome or even if someone points out suitable resources on the net I would be obliged.

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Tom C
Moderator

Posts: 392
From:Brodheadsville, PA USA
Registered: Jun 2001

posted September 25, 2004 08:36 AM     Click Here to See the Profile for Tom C   Click Here to Email Tom C     Edit/Delete Message   Reply w/Quote
PET is extremely sensitive to moisture. Ideally the regrind should be dried to below 0.025% moisture content before extrusion. Many extrude regrind without drying, becasue of the difficulty in drying it. This technique requires a vacuum vent on the extruder. Under these conditions the viscosity can be maintained on average, but there will be a lot of varibility. Without out drying and/or a vacuum vent the results will be poor.

One of the most difficult challanges is just getting the regind into the extruder if you are using flake. A regular extruder hopper will not work as the material compresses and locks up.

In the extruder a high compression ratio screw will work best. Extruder zone temperatures run 520-540F.

Tom Cunningham
Extrusion Technical Services www.ExtrusionTech.com

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Bob Cunningham
Senior Member

Posts: 92
From:Amesbury, Mass
Registered: Nov 2002

posted September 28, 2004 04:29 PM     Click Here to See the Profile for Bob Cunningham   Click Here to Email Bob Cunningham     Edit/Delete Message   Reply w/Quote
You may want to consider contacting Erema- http://www.erema.at/ . Their Vacurema was designed specifically for this purpose. Even if you are not looking to purchase a machine, you can look at how it is done.

You will see that there is much more than just a screw involved- they preheat the material, pre-dry it, size-reduce the material, apply a vacuum to the whole system, cram it into the screw, and use a vent on the screw.

-Bob Cunningham

[This message has been edited by Bob Cunningham (edited September 28, 2004).]

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Tom C
Moderator

Posts: 392
From:Brodheadsville, PA USA
Registered: Jun 2001

posted September 28, 2004 09:27 PM     Click Here to See the Profile for Tom C   Click Here to Email Tom C     Edit/Delete Message   Reply w/Quote
Apparently we Cunnighams have this one covered.

Tom

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Steve H
Moderator

Posts: 320
From:New Zealand
Registered: Jun 2001

posted September 29, 2004 05:29 AM     Click Here to See the Profile for Steve H   Click Here to Email Steve H     Edit/Delete Message   Reply w/Quote
quote:
Apparently we Cunnighams have this one covered.

Well not quite boys esskay, I dislike the vented approach to processing/reprocessing APET.
By processing APET with moisture in it, you reverse the chemical process used to make it, (how bright is that ???), so I would vote Erema as a first choice, and predried/crystallized using a vacuum dryer second. Either way you should investigate chain extenders to improve the IV of the finished product (sheet?), Clariant and CIBA both offer these additives.
BTW, welcome to the single screw forum

Steve

[This message has been edited by Steve H (edited September 29, 2004).]

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Tom C
Moderator

Posts: 392
From:Brodheadsville, PA USA
Registered: Jun 2001

posted September 29, 2004 07:40 AM     Click Here to See the Profile for Tom C   Click Here to Email Tom C     Edit/Delete Message   Reply w/Quote
Exactly how does the Erema process work? To my surprise, there are no pictures or process descriptions on the web site. From what I have seen in the past they use a mechanical shearing system to work the flakes, drive the moisture out, and feed the extruder. A nice process if it works.

A similar concept has been developed to use on fully intermeshing corotating twin screw extruders. The material is worked in it's solid state and water is vented out. The polymer is then melted, vacuum vented and extruded.

Steve, as stated I am aware of the moisture issue. The degradation of PET in extrusion is not a very fast reaction. This allows initial meting of the PET with some, but not complete degradation. The application of vacuum will patially repolymerize the PET, and assure a reasonable viscosity. The IV results will be variable due to variability in starting moisture content, degradation, and repolyimerization. Do not expect to be able to use PET recovered this way in blow molding. It is acceptable for injection molding compounds.

Tom Cunningham www.ExtrusionTech.com


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Steve H
Moderator

Posts: 320
From:New Zealand
Registered: Jun 2001

posted September 29, 2004 03:22 PM     Click Here to See the Profile for Steve H   Click Here to Email Steve H     Edit/Delete Message   Reply w/Quote
quote:
From what I have seen in the past they use a mechanical shearing system to work the flakes, drive the moisture out, and feed the extruder.

Pretty close, Tom. The hopper where this is taking place is under a vacuum. It's an elegant solution to recycling APET.
Processing APET on a vented extruder without predrying lowers it's IV, while this may not be much of a problem first time round, it will become a problem on subsequent reuses.
With the Erema process, there is no loss in IV, and when used with chain extenders, the materials IV is raised. Erema are using their process to injection mould preforms for bottle blow moulding. The other plus with the Erema process is that it has FDA approval to recycle for food contact applications.

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TomBlack
Moderator

Posts: 55
From:
Registered: Jul 2002

posted September 30, 2004 06:01 PM     Click Here to See the Profile for TomBlack   Click Here to Email TomBlack     Edit/Delete Message   Reply w/Quote
While agree w/ what's been mentioned so far, I wouldn't necessarily consider it to be mutually exclusive. Many processors I've worked w/ will pre-dry/crystallize PET to maintain IV and avoid feed problems, then vacuum vent as well (as an insurance policy for IV degradation).

------------------
Thomas Black
PPS, Inc.

www.ppsincorp.com

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Bob Cunningham
Senior Member

Posts: 92
From:Amesbury, Mass
Registered: Nov 2002

posted September 30, 2004 07:15 PM     Click Here to See the Profile for Bob Cunningham   Click Here to Email Bob Cunningham     Edit/Delete Message   Reply w/Quote
In one of their machines spefically designed for PET (i.e. their "bottle to bottle" machines), their repelletizing process will actually increase the IV, so that you can re-use the pellets in new bottles. They expose the flake to vacuum and heat for long periods, and the screw is very low sheer (with a few special tricks).

And no, they don't use any chain extenders or anything. The PET that you put in is the PET that you get out (except for the moisture/volitiles, etc., that come out under vacuum), with a higher IV.

They also have processes for PET fiber (which have more oils, etc.).

-Bob Cunningham

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mik henson
Member

Posts: 1
From:uk
Registered: Oct 2004

posted October 26, 2004 04:45 AM     Click Here to See the Profile for mik henson   Click Here to Email mik henson     Edit/Delete Message   Reply w/Quote
we extruded recycled bottles ,main thing is you need a good dryer/crystalizer good feed section and a screen

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