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Heterogeneous Nucleation of Ice in Dispersed Phase of Water-in-Decane Emulsion

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Abstract—

A model developed for the description of experimental data on heterogeneous nucleation in disperse systems with metastable dispersed phases is applied to the case of ice nucleation in a water emulsion in decane under methane pressure . Activity spectra are obtained for ice-forming particles in the water–decane–methane system. The frequency of ice nucleation on these particles is calculated. Activities of ice- and clathrate-forming particles in this system are compared. It is shown that small amounts of active particles incorporated into the system from an environment can have a significant effect on ice nucleation.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    V. A. Shestakov, V. I. Kosyakov, A. Yu. Manakov, A. S. Stoporev & E. V. Grachev

  2. Novosibirsk State University, 630090, Novosibirsk, Russia

    A. Yu. Manakov & A. S. Stoporev

Authors
  1. V. A. Shestakov
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  2. V. I. Kosyakov
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  3. A. Yu. Manakov
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  4. A. S. Stoporev
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  5. E. V. Grachev
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Corresponding author

Correspondence to V. A. Shestakov.

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Translated by K. Aleksanyan

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Shestakov, V.A., Kosyakov, V.I., Manakov, A.Y. et al. Heterogeneous Nucleation of Ice in Dispersed Phase of Water-in-Decane Emulsion. Colloid J 81, 199–203 (2019). https://doi.org/10.1134/S1061933X19010113

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  • DOI: https://doi.org/10.1134/S1061933X19010113

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