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Multipurpose Organically Modified Carbon Nanotubes: From Functionalization to Nanotube Composites

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Institute of Materials Science, N.C.S.R. “Demokritos”, GR-15310 Agia Paraskevi Athens, Greece, Department of Materials Science and Engineering, University of Ioannina, GR-45110 Ioannina, Greece, and Center of Excellence for Nanostructured Materials (CENMAT), Dipartimento di Scienze Farmaceutiche, INSTM, Universita di Trieste, Piazzale Europa 1, 34127 Trieste, Italy
†N.C.S.R. “Demokritos”.
‡University of Ioannina.
§Universita di Trieste.
Cite this: J. Am. Chem. Soc. 2008, 130, 27, 8733–8740
Publication Date (Web):June 14, 2008
https://doi.org/10.1021/ja8002952
Copyright © 2008 American Chemical Society

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    Abstract

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    We show that covalent functionalization of carbon nanotubes (CNTs) via 1,3-dipolar cycloaddition is a powerful method for enhancing the ability to process CNTs and facilitating the preparation of hybrid composites, which is achieved solely by mixing. CNTs were functionalized with phenol groups, providing stable dispersions in a range of polar solvents, including water. Additionally, the functionalized CNTs could easily be combined with polymers and layered aluminosilicate clay minerals to give homogeneous, coherent, transparent CNT thin films and gels.

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