Novel self-organization mechanism in ultrathin liquid films: theory and experiment

Phys Rev Lett. 2008 Jul 4;101(1):017802. doi: 10.1103/PhysRevLett.101.017802. Epub 2008 Jul 2.

Abstract

When an ultrathin metal film of thickness h (<20 nm) is melted by a nanosecond pulsed laser, the film temperature is a nonmonotonic function of h and achieves its maximum at a certain thickness h*. This is a consequence of the h and time dependence of energy absorption and heat flow. Linear stability analysis and nonlinear dynamical simulations that incorporate such intrinsic interfacial thermal gradients predict a characteristic pattern length scale Lambda that decreases for h>h*, in contrast to the classical spinodal dewetting behavior where Lambda increases monotonically as h2. These predictions agree well with experimental observations for Co and Fe films on SiO2.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Cobalt / chemistry
  • Iron / chemistry
  • Models, Chemical*
  • Nanostructures / chemistry*
  • Nanotechnology / methods*
  • Silicon Dioxide / chemistry
  • Thermodynamics

Substances

  • Cobalt
  • Silicon Dioxide
  • Iron