ACS Publications. Most Trusted. Most Cited. Most Read

OR SEARCH CITATIONS

My Activity
Publications
CONTENT TYPES

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Phys. Chem. C 2017, 121, 6, 3607-3614
RETURN TO ISSUEPREVArticleNEXT

Hydroxyl-Induced Partial Charge States of Single Porphyrins on Titania Rutile

View Author Information
† Department of Physics, University of Basel, Klingelbergstrasse 82, 4056 Basel, Switzerland
‡ Department of Physics, Shahid Beheshti University, Evin, 19839 Teheran, Iran
§ Faculty of Physics, Astronomy and Applied Computer Science, Jagiellonian University, Ul. S. Łojasiewicza 11, 30-348 Krakow, Poland
*E-mail: [email protected]
*E-mail: [email protected]
Cite this: J. Phys. Chem. C 2017, 121, 6, 3607–3614
Publication Date (Web):January 19, 2017
https://doi.org/10.1021/acs.jpcc.6b11873
Copyright © 2017 American Chemical Society
Request reuse permissions

    Article Views

    929

    Altmetric

    -

    Citations

    24
    LEARN ABOUT THESE METRICS
    Other access options
    Get e-Alerts
    SUBJECTS:

    Abstract

    Abstract Image

    The adsorption of Cu–porphyrin derivatives terminated with peripheral carboxyphenyl side groups on hydroxylated TiO2(110) surfaces is investigated by combined scanning tunneling microscopy (STM), atomic force microscopy (AFM), and density functional theory (DFT). Two distinct contrasts of the molecules are revealed by STM and tunneling spectroscopy. Via single-molecule manipulations, the origin of these peculiar contrasts is found to arise from the presence or not of hydroxyl groups below the molecules. Hence, the electronic coupling of the molecule with the underlying TiO2 surface is locally modified altering the amount of charge transfer and thus their charge state at the molecular scale. Our results particularly underline the fundamental role of hydroxyls of TiO2 on the charge state of adsorbed organic molecules potentially used in dye-sensitized solar cells.

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. You can change your affiliated institution below.

    Cited By

    This article is cited by 24 publications.

    1. Qiang Zhu, Yuuki Adachi, Yasuhiro Sugawara, Yanjun Li. Tip-Induced Dynamic Behaviors of a Water Molecule and Hydroxyl on the Rutile TiO2(110) Surface. The Journal of Physical Chemistry C 2022, 126 (31) , 13062-13068. https://doi.org/10.1021/acs.jpcc.1c08935
    2. Masato Miyazaki, Yasuhiro Sugawara, Yan Jun Li. Charge Behavior of Terminal Hydroxyl on Rutile TiO2(110). Langmuir 2021, 37 (35) , 10588-10593. https://doi.org/10.1021/acs.langmuir.1c01845
    3. Peter Jacobson, Deborah Prezzi, Dongdong Liu, Monika Schied, James M. Tour, Stefano Corni, Arrigo Calzolari, Elisa Molinari, Leonhard Grill. Adsorption and Motion of Single Molecular Motors on TiO2(110). The Journal of Physical Chemistry C 2020, 124 (45) , 24776-24785. https://doi.org/10.1021/acs.jpcc.0c07065
    4. Cynthia C. Fernández, Daniel Wechsler, Tulio C. R. Rocha, Hans-Peter Steinrück, Ole Lytken, Federico J. Williams. Adsorption of Phosphonic-Acid-Functionalized Porphyrin Molecules on TiO2(110). The Journal of Physical Chemistry C 2019, 123 (17) , 10974-10980. https://doi.org/10.1021/acs.jpcc.9b01019
    5. Johannes Schneider, Thomas Berger, Oliver Diwald. Reactive Porphyrin Adsorption on TiO2 Anatase Particles: Solvent Assistance and the Effect of Water Addition. ACS Applied Materials & Interfaces 2018, 10 (19) , 16836-16842. https://doi.org/10.1021/acsami.8b00894
    6. Luca Schio, Gregor Bavdek, Cesare Grazioli, Carolina Gutiérrez Bolaños, Andrea Goldoni, Andrea Vittadini, Massimo Tormen, Luca Floreano. Role of axial coordination in the adsorption configuration of M(II)-tetraphenylporphyrins (M = Co, Ni, Cu, Zn) on r-TiO 2 (110). Applied Surface Science 2023, 616 , 156548. https://doi.org/10.1016/j.apsusc.2023.156548
    7. . Imaging Ultraviolet Light-Induced Oxygen Vacancy Diffusion on TiO 2 (110) Surface. Chinese Journal of Chemical Physics 2023https://doi.org/10.1063/1674-0068/cjcp2302012
    8. Maximilian Ammon, Mirunalini Devarajulu, Yi Liu, Martin Gurrath, Dominik Lungerich, Norbert Jux, Bernd Meyer, Sabine Maier. Adsorption and self-assembly of a mono-cyano Zn-tetraphenylporphyrin derivative on KBr(001) and MgO(001). Surface Science 2022, 723 , 122097. https://doi.org/10.1016/j.susc.2022.122097
    9. Luca Schio, Daniel Forrer, Maurizio Casarin, Andrea Goldoni, Celia Rogero, Andrea Vittadini, Luca Floreano. On surface chemical reactions of free-base and titanyl porphyrins with r-TiO 2 (110): a unified picture. Physical Chemistry Chemical Physics 2022, 24 (21) , 12719-12744. https://doi.org/10.1039/D2CP01073A
    10. Yuuki Adachi, Hongqian Sang, Yasuhiro Sugawara, Yan Jun Li. Single hydrogen atom manipulation for reversible deprotonation of water on a rutile TiO2 (110) surface. Communications Chemistry 2021, 4 (1) https://doi.org/10.1038/s42004-020-00444-4
    11. Markus K. Kremer, Daniel Forrer, Celia Rogero, Luca Floreano, Andrea Vittadini. Digging Ti interstitials at the r-TiO2(1 1 0) surface: Mechanism of porphyrin Ti sequestration by iminic N nucleophilic attack. Applied Surface Science 2021, 564 , 150403. https://doi.org/10.1016/j.apsusc.2021.150403
    12. Qigang Zhong, Xuechao Li, Haiming Zhang, Lifeng Chi. Noncontact atomic force microscopy: Bond imaging and beyond. Surface Science Reports 2020, 75 (4) , 100509. https://doi.org/10.1016/j.surfrep.2020.100509
    13. Lukasz Bodek, Mads Engelund, Aleksandra Cebrat, Bartosz Such. Adsorption behavior of tin phthalocyanine onto the (110) face of rutile TiO 2. Beilstein Journal of Nanotechnology 2020, 11 , 821-828. https://doi.org/10.3762/bjnano.11.67
    14. Sweetlana Fremy-Koch, Ali Sadeghi, Rémy Pawlak, Shigeki Kawai, Alexis Baratoff, Stefan Goedecker, Ernst Meyer, Thilo Glatzel. Controlled switching of a single CuPc molecule on Cu(111) at low temperature. Physical Review B 2019, 100 (15) https://doi.org/10.1103/PhysRevB.100.155427
    15. Sara Freund, Antoine Hinaut, Nathalie Marinakis, Edwin C Constable, Ernst Meyer, Catherine E Housecroft, Thilo Glatzel. Comparing a porphyrin- and a coumarin-based dye adsorbed on NiO(001). Beilstein Journal of Nanotechnology 2019, 10 , 874-881. https://doi.org/10.3762/bjnano.10.88
    16. Lukasz Zajac, Lukasz Bodek, Bartosz Such. Adsorption behavior of Zn porphyrins on a (1 0 1) face of anatase TiO2. Applied Surface Science 2018, 443 , 452-457. https://doi.org/10.1016/j.apsusc.2018.02.278
    17. Leo Gross, Bruno Schuler, Niko Pavliček, Shadi Fatayer, Zsolt Majzik, Nikolaj Moll, Diego Peña, Gerhard Meyer. Rasterkraftmikroskopie für die molekulare Strukturaufklärung. Angewandte Chemie 2018, 130 (15) , 3950-3972. https://doi.org/10.1002/ange.201703509
    18. Leo Gross, Bruno Schuler, Niko Pavliček, Shadi Fatayer, Zsolt Majzik, Nikolaj Moll, Diego Peña, Gerhard Meyer. Atomic Force Microscopy for Molecular Structure Elucidation. Angewandte Chemie International Edition 2018, 57 (15) , 3888-3908. https://doi.org/10.1002/anie.201703509
    19. Zoltán Dudás, Eugenia Fagadar-Cosma, Adél Len, Loránd Románszki, László Almásy, Beatrice Vlad-Oros, Daniela Dascălu, Andraž Krajnc, Manfred Kriechbaum, Andrei Kuncser. Improved Optical and Morphological Properties of Vinyl-Substituted Hybrid Silica Materials Incorporating a Zn-Metalloporphyrin. Materials 2018, 11 (4) , 565. https://doi.org/10.3390/ma11040565
    20. Sascha Sadewasser, Thilo Glatzel. Experimental Technique and Working Modes. 2018, 3-22. https://doi.org/10.1007/978-3-319-75687-5_1
    21. Kohei Tada, Yasushi Maeda, Hiroyuki Ozaki, Shingo Tanaka, Shin-ichi Yamazaki. Theoretical investigation on the interaction between Rh III octaethylporphyrin and a graphite basal surface: a comparison study of DFT, DFT-D, and AFM. Physical Chemistry Chemical Physics 2018, 20 (30) , 20235-20246. https://doi.org/10.1039/C8CP02923G
    22. Sara Freund, Antoine Hinaut, Nathalie Marinakis, Edwin C Constable, Ernst Meyer, Catherine E Housecroft, Thilo Glatzel. Anchoring of a dye precursor on NiO(001) studied by non-contact atomic force microscopy. Beilstein Journal of Nanotechnology 2018, 9 , 242-249. https://doi.org/10.3762/bjnano.9.26
    23. Res Jöhr, Antoine Hinaut, Rémy Pawlak, Łukasz Zajac, Piotr Olszowski, Bartosz Such, Thilo Glatzel, Jun Zhang, Matthias Muntwiler, Jesse J. Bergkamp, Luis-Manuel Mateo, Silvio Decurtins, Shi-Xia Liu, Ernst Meyer. Thermally induced anchoring of a zinc-carboxyphenylporphyrin on rutile TiO2 (110). The Journal of Chemical Physics 2017, 146 (18) https://doi.org/10.1063/1.4982936
    24. Giacomo Lovat, Daniel Forrer, Mikel Abadia, Marcos Dominguez, Maurizio Casarin, Celia Rogero, Andrea Vittadini, Luca Floreano. Very high temperature tiling of tetraphenylporphyrin on rutile TiO 2 (110). Nanoscale 2017, 9 (32) , 11694-11704. https://doi.org/10.1039/C7NR04093H
    Download PDF

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    You’ve supercharged your research process with ACS and Mendeley!

    STEP 1:
    Click to create an ACS ID

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    MENDELEY PAIRING EXPIRED
    Your Mendeley pairing has expired. Please reconnect