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Zirconium Arene-Phosphonates:  Chemical and Structural Characterization of 2-Naphthyl- and 2-Anthracenylphosphonate Systems

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Department of Chemistry, University of Vermont, Burlington, Vermont 05405
Cite this: Inorg. Chem. 2005, 44, 6, 2067–2073
Publication Date (Web):February 23, 2005
https://doi.org/10.1021/ic0400282
Copyright © 2005 American Chemical Society
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    Abstract

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    Several new zirconium phosphonates incorporating naphthalene and anthracene ring systems and having the general formula Zr(O3PR)1(O3PR‘)1 [R and R‘ = −C10H7, −C14H9, −OC4H9, and −OC2H5] have been synthesized. These compounds were chemically characterized using thermal gravimetric analysis (percentage of organic content), infrared spectroscopy (presence of the desired organic functional groups), and solid-state 31P NMR (phosphorus environments), while the structural parameters were determined using X-ray powder diffraction (interlayer d spacings). The d spacings of the zirconium bis(phosphonates) correlate well with a simple predictive model based on the effective length of the organic functional group. The zirconium mixed phosphonates examined are single-phase structures with random mixtures of the organic moieties within the interlayer and possess d spacings that are between those of the two parent zirconium bis(phosphonates).

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    †

     Current Address:  School of Science, Penn State Erie, The Behrend College, Erie, PA 16563.

    *

     Author to whom correspondence should be addressed. E-mail: [email protected].

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    Synthetic methodologies for zirconium bis(phosphonates) and zirconium mixed phosphonates, phosphonic acids, and precursors to phosphonic acids, not specifically described in the paper. Sets of TGA traces, IR spectra, solid-state 31P NMR spectra, and XRD patterns for compounds examined but not explicitly displayed in the paper, given as Figures 1S−4S, respectively. This material is available free of charge via the Internet at http://pubs.acs.org.

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