ACS Publications. Most Trusted. Most Cited. Most Read

OR SEARCH CITATIONS

My Activity
Publications
CONTENT TYPES

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:Anal. Chem. 2011, 83, 4, 1214-1223
RETURN TO ISSUEPREVArticleNEXT

Degradation Process of Lead Chromate in Paintings by Vincent van Gogh Studied by Means of Synchrotron X-ray Spectromicroscopy and Related Methods. 1. Artificially Aged Model Samples

View Author Information
‡ †Dipartimento di Chimica and ‡CNR di Scienze e Tecnologie Molecolari (CNR-ISTM), Università degli Studi di Perugia, via Elce di Sotto 8, I-06123 Perugia, Italy
§ §Department of Chemistry, University of Antwerp, Universiteitsplein 1, B-2610 Wilrijk, Belgium
⊥ ⊥Department of Physics, Electron Microscopy For Materials Science (EMAT), University of Antwerp, Groenenborgerlaan 171, B-2020 Antwerp, Belgium
Department of Materials Science and Engineering, Delft University of Technology, Mekelweg 2, NL-2628CD Delft, The Netherlands
△ Centre de Recherche et de Restauration des Musées de France, CNRS UMR171, Palais du Louvre, Porte des Lions, 14 Quai François Mitterrand, F-75001 Paris, France
▲ European Synchrotron Radiation Facility, Polygone Scientifique Louis Néel -6, rue Jules Horowitz − F-38000 Grenoble, France
*Phone: +32 3 820 2373. Fax: +32 3 820 23 76. E-mail: [email protected]
Cite this: Anal. Chem. 2011, 83, 4, 1214–1223
Publication Date (Web):February 14, 2011
https://doi.org/10.1021/ac102424h
Copyright © 2011 American Chemical Society
Request reuse permissions

    Article Views

    3799

    Altmetric

    -

    Citations

    113
    LEARN ABOUT THESE METRICS
    Other access options
    Get e-Alerts
    SUBJECTS:

    Abstract

    Abstract Image

    On several paintings by artists of the end of the 19th century and the beginning of the 20th Century a darkening of the original yellow areas, painted with the chrome yellow pigment (PbCrO4, PbCrO4·xPbSO4, or PbCrO4·xPbO) is observed. The most famous of these are the various Sunflowers paintings Vincent van Gogh made during his career. In the first part of this work, we attempt to elucidate the degradation process of chrome yellow by studying artificially aged model samples. In view of the very thin (1−3 μm) alteration layers that are formed, high lateral resolution spectroscopic methods such as microscopic X-ray absorption near edge (μ-XANES), X-ray fluorescence spectrometry (μ-XRF), and electron energy loss spectrometry (EELS) were employed. Some of these use synchrotron radiation (SR). Additionally, microscopic SR X-ray diffraction (SR μ-XRD), μ-Raman, and mid-FTIR spectroscopy were employed to completely characterize the samples. The formation of Cr(III) compounds at the surface of the chrome yellow paint layers is particularly observed in one aged model sample taken from a historic paint tube (ca. 1914). About two-thirds of the chromium that is present at the surface has reduced from the hexavalent to the trivalent state. The EELS and μ-XANES spectra are consistent with the presence of Cr2O3·2H2O (viridian). Moreover, as demonstrated by μ-XANES, the presence of another Cr(III) compound, such as either Cr2(SO4)3·H2O or (CH3CO2)7Cr3(OH)2 [chromium(III) acetate hydroxide], is likely.

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. You can change your affiliated institution below.

    Cited By

    This article is cited by 113 publications.

    1. Jeffrey E. Fieberg . Development and Implementation of Molecular Modernism, a “Chemistry and Art” Course with Travel Components in France or the United States. , 235-282. https://doi.org/10.1021/bk-2021-1386.ch011
    2. Letizia Monico, Marine Cotte, Frederik Vanmeert, Lucia Amidani, Koen Janssens, Gert Nuyts, Jan Garrevoet, Gerald Falkenberg, Pieter Glatzel, Aldo Romani, Costanza Miliani. Damages Induced by Synchrotron Radiation-Based X-ray Microanalysis in Chrome Yellow Paints and Related Cr-Compounds: Assessment, Quantification, and Mitigation Strategies. Analytical Chemistry 2020, 92 (20) , 14164-14173. https://doi.org/10.1021/acs.analchem.0c03251
    3. Federica Frati, Myrtille O. J. Y. Hunault, Frank M. F. de Groot. Oxygen K-edge X-ray Absorption Spectra. Chemical Reviews 2020, 120 (9) , 4056-4110. https://doi.org/10.1021/acs.chemrev.9b00439
    4. Han Gao, Peiyun Wei, Huiting Liu, Mingce Long, Heyun Fu, Xiaolei Qu. Sunlight-Mediated Lead and Chromium Release from Commercial Lead Chromate Pigments in Aqueous Phase. Environmental Science & Technology 2019, 53 (9) , 4931-4939. https://doi.org/10.1021/acs.est.8b06839
    5. Letizia Monico, Lorenzo Sorace, Marine Cotte, Wout de Nolf, Koen Janssens, Aldo Romani, Costanza Miliani. Disclosing the Binding Medium Effects and the Pigment Solubility in the (Photo)reduction Process of Chrome Yellows (PbCrO4/PbCr1–xSxO4). ACS Omega 2019, 4 (4) , 6607-6619. https://doi.org/10.1021/acsomega.8b03669
    6. Marta Ghirardello, Sara Mosca, Javier Marti-Rujas, Luca Nardo, Aviva Burnstock, Austin Nevin, Maria Bondani, Lucia Toniolo, Gianluca Valentini, Daniela Comelli. Time-Resolved Photoluminescence Microscopy Combined with X-ray Analyses and Raman Spectroscopy Sheds Light on the Imperfect Synthesis of Historical Cadmium Pigments. Analytical Chemistry 2018, 90 (18) , 10771-10779. https://doi.org/10.1021/acs.analchem.8b01666
    7. Vanoushe Rahemi, Nasrin Sarmadian, Willemien Anaf, Koen Janssens, Dirk Lamoen, Bart Partoens, and Karolien De Wael . Unique Optoelectronic Structure and Photoreduction Properties of Sulfur-Doped Lead Chromates Explaining Their Instability in Paintings. Analytical Chemistry 2017, 89 (6) , 3326-3334. https://doi.org/10.1021/acs.analchem.6b03803
    8. Letizia Monico, Koen Janssens, Frederik Vanmeert, Marine Cotte, Brunetto Giovanni Brunetti, Geert Van der Snickt, Margje Leeuwestein, Johanna Salvant Plisson, Michel Menu, and Costanza Miliani . Degradation Process of Lead Chromate in Paintings by Vincent van Gogh Studied by Means of Spectromicroscopic Methods. Part 5. Effects of Nonoriginal Surface Coatings into the Nature and Distribution of Chromium and Sulfur Species in Chrome Yellow Paints. Analytical Chemistry 2014, 86 (21) , 10804-10811. https://doi.org/10.1021/ac502841g
    9. Willemien Anaf, Stanislav Trashin, Olivier Schalm, Dennis van Dorp, Koen Janssens, and Karolien De Wael . Electrochemical Photodegradation Study of Semiconductor Pigments: Influence of Environmental Parameters. Analytical Chemistry 2014, 86 (19) , 9742-9748. https://doi.org/10.1021/ac502303z
    10. Letizia Monico, Koen Janssens, Costanza Miliani, Brunetto Giovanni Brunetti, Manuela Vagnini, Frederik Vanmeert, Gerald Falkenberg, Artem Abakumov, Yinggang Lu, He Tian, Johan Verbeeck, Marie Radepont, Marine Cotte, Ella Hendriks, Muriel Geldof, Luuk van der Loeff, Johanna Salvant, and Michel Menu . Degradation Process of Lead Chromate in Paintings by Vincent van Gogh Studied by Means of Spectromicroscopic Methods. 3. Synthesis, Characterization, and Detection of Different Crystal Forms of the Chrome Yellow Pigment. Analytical Chemistry 2013, 85 (2) , 851-859. https://doi.org/10.1021/ac302158b
    11. Letizia Monico, Koen Janssens, Costanza Miliani, Geert Van der Snickt, Brunetto Giovanni Brunetti, Mariangela Cestelli Guidi, Marie Radepont, and Marine Cotte . Degradation Process of Lead Chromate in Paintings by Vincent van Gogh Studied by Means of Spectromicroscopic Methods. 4. Artificial Aging of Model Samples of Co-Precipitates of Lead Chromate and Lead Sulfate. Analytical Chemistry 2013, 85 (2) , 860-867. https://doi.org/10.1021/ac3021592
    12. Daryl L. Howard, Martin D. de Jonge, Deborah Lau, David Hay, Michael Varcoe-Cocks, Chris G. Ryan, Robin Kirkham, Gareth Moorhead, David Paterson, and David Thurrowgood . High-Definition X-ray Fluorescence Elemental Mapping of Paintings. Analytical Chemistry 2012, 84 (7) , 3278-3286. https://doi.org/10.1021/ac203462h
    13. Kouichi Tsuji and Kazuhiko Nakano , Yoshio Takahashi , Kouichi Hayashi , Chul-Un Ro . X-ray Spectrometry. Analytical Chemistry 2012, 84 (2) , 636-668. https://doi.org/10.1021/ac202871b
    14. Astrid Harth. X-ray fluorescence (XRF) on painted heritage objects: a review using topic modeling. Heritage Science 2024, 12 (1) https://doi.org/10.1186/s40494-024-01135-2
    15. Mariam Akram, Malika Rani, Kiran Batool, Mohamed A Habila, Mika Sillanpää, Aqeel Ahmad Shah, Rubia Shafique. Lead integrated two-dimensional (MXene/PbCrO 4 ) nanocomposite designed for energy storage and photocatalytic degradation applications. Physica Scripta 2024, 99 (1) , 015902. https://doi.org/10.1088/1402-4896/ad0fcd
    16. Han Gao, Huixin Li, Xinwei Zhou, Jing Wei, Xiaolei Qu, Tao Long. Effect of low molecular weight organic acids on the lead and chromium release from widely-used lead chromate pigments under sunlight irradiation. Environmental Pollution 2023, 337 , 122553. https://doi.org/10.1016/j.envpol.2023.122553
    17. Ye Ri Gwon, Jinseok Kang, Seunghoe Choe, Sung Ki Cho. The Photoelectrochemical Response of PbCrO 4 Thin Film Fabricated Using Pechini Method: The Effect of Nitrate Decomposition in Precursor Solution. Journal of The Electrochemical Society 2023, 170 (10) , 106504. https://doi.org/10.1149/1945-7111/ad00dc
    18. Letizia Monico, Francesco d'Acapito, Marine Cotte, Koen Janssens, Aldo Romani, Giulia Ricci, Costanza Miliani, Laura Cartechini. Total electron yield (TEY) detection mode Cr K-edge XANES spectroscopy as a direct method to probe the composition of the surface of darkened chrome yellow (PbCr1-xSxO4) and potassium chromate paints. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 2023, 539 , 141-147. https://doi.org/10.1016/j.nimb.2023.03.040
    19. Anna Klisińska-Kopacz, Piotr Frączek, Michał Obarzanowski, Janusz Czop. Non-Invasive Study of Pigment Palette Used by Olga Boznańska Investigated with Analytical Imaging, XRF, and FTIR Spectroscopy. Heritage 2023, 6 (2) , 1429-1443. https://doi.org/10.3390/heritage6020078
    20. Howell G. M. Edwards, Peter Vandenabeele, Philippe Colomban. Pigments, Dyes and Colouring Agents. 2023, 53-106. https://doi.org/10.1007/978-3-031-14379-3_5
    21. Howell G. M. Edwards, Peter Vandenabeele, Philippe Colomban. From Frescoes to Paintings. 2023, 169-214. https://doi.org/10.1007/978-3-031-14379-3_9
    22. Maria José Alves Oliveira, Larissa Otubo, Adriana Pires, Rodrigo Fernando Brambilla, Ana Cristina Carvalho, Paulo S. Santos, Almir Oliveira Neto, Pablo Vasquez. Silver nanoparticles-based hydrogels synthetized by ionizing radiation for cleaning of tangible cultural heritage surfaces. Radiation Physics and Chemistry 2022, 199 , 110345. https://doi.org/10.1016/j.radphyschem.2022.110345
    23. Letizia Monico, Silvia Prati, Giorgia Sciutto, Emilio Catelli, Aldo Romani, Diego Quintero Balbas, Zelan Li, Steven De Meyer, Gert Nuyts, Koen Janssens, Marine Cotte, Jan Garrevoet, Gerald Falkenberg, Vanessa Isabel Tardillo Suarez, Remi Tucoulou, Rocco Mazzeo. Development of a multi-method analytical approach based on the combination of synchrotron radiation X-ray micro-analytical techniques and vibrational micro-spectroscopy methods to unveil the causes and mechanism of darkening of “fake-gilded” decorations in a Cimabue painting. Journal of Analytical Atomic Spectrometry 2022, 37 (1) , 114-129. https://doi.org/10.1039/D1JA00271F
    24. Giovanna Vasco, Antonio Serra, Daniela Manno, Giovanni Buccolieri, Lucio Calcagnile, Lidiana Miotto, Ludovico Valli, Alessandro Buccolieri. Diagnostic investigation to support the restoration of the polychrome terracotta relief “Madonna and Child” in Piove di Sacco (Padova, Italy). Journal of Cultural Heritage 2022, 53 , 80-87. https://doi.org/10.1016/j.culher.2021.11.009
    25. Selwin Hageraats, Mathieu Thoury, Marine Cotte, Loïc Bertrand, Koen Janssens, Katrien Keune. Microchemical Imaging of Oil Paint Composition and Degradation: State-of-the-Art and Future Prospects. 2022, 359-418. https://doi.org/10.1007/978-3-030-86865-9_12
    26. Francesco D’Acapito. X-Ray Absorption Spectroscopy (XAS) Applied to Cultural Heritage. 2022, 45-67. https://doi.org/10.1007/978-3-030-60016-7_4
    27. David V. Sampaio, Rafaella B. Pena, Benjamin J.A. Moulton, Marcos V. Rezende, Deyvid do C. Silva, Ronaldo S. Silva, Thiago R. da Cunha, Valmor R. Mastelaro, Edgar D. Zanotto, Paulo S. Pizani. Chromium in lead metasilicate glass: Solubility, valence, and local environment via multiple spectroscopy. Ceramics International 2022, 48 (1) , 173-178. https://doi.org/10.1016/j.ceramint.2021.08.377
    28. Elisabetta Gliozzo, Corina Ionescu. Pigments—Lead-based whites, reds, yellows and oranges and their alteration phases. Archaeological and Anthropological Sciences 2022, 14 (1) https://doi.org/10.1007/s12520-021-01407-z
    29. Ali Mahmoodi, Zahra Jiryaei, Ayda Dadras, Manouchehr Khorasani, Xianming Shi. A hybrid yellow nanopigment as an environmentally sound alternative to lead chromate pigment for pavement markings. Journal of Cleaner Production 2021, 319 , 128733. https://doi.org/10.1016/j.jclepro.2021.128733
    30. Ilaria Costantini, Kepa Castro, Maria Dolores Rodriguez-Laso, Juan Manuel Madariaga, Gorka Arana. Non-Destructive Analytical Investigation of Decorative Wallpapers Samples of the Nineteenth Century before Their Restoration. Sensors 2021, 21 (13) , 4416. https://doi.org/10.3390/s21134416
    31. Mady Elbahri, Shahin Homaeigohar, Mhd Adel Assad. Reflective Coloration from Structural Plasmonic to Disordered Polarizonic. Advanced Photonics Research 2021, 2 (7) https://doi.org/10.1002/adpr.202100009
    32. Juan Manuel Madariaga. X-Ray Fluorescence (XRF) Techniques. 2021, 23-44. https://doi.org/10.1039/9781788015974-00023
    33. A. Domínguez-Vidal, M. J. Ayora-Cañada. Synchrotron Radiation Sources for Characterization at the Microscopic Level. 2021, 75-98. https://doi.org/10.1039/9781788015974-00075
    34. Jinseok Kang, Ye Ri Gwon, Sung Ki Cho. Photoelectrochemical water oxidation on PbCrO4 thin film photoanode fabricated via Pechini method: Various solution-processes for PbCrO4 film synthesis. Journal of Electroanalytical Chemistry 2020, 878 , 114601. https://doi.org/10.1016/j.jelechem.2020.114601
    35. A.E. Pradas del Real, A. Pérez-Sanz, P. García-Gonzalo, H. Castillo-Michel, M.J. Gismera, M.C. Lobo. Evaluating Cr behaviour in two different polluted soils: Mechanisms and implications for soil functionality. Journal of Environmental Management 2020, 276 , 111073. https://doi.org/10.1016/j.jenvman.2020.111073
    36. Lambert Baij, Joen Hermans, Bronwyn Ormsby, Petria Noble, Piet Iedema, Katrien Keune. A review of solvent action on oil paint. Heritage Science 2020, 8 (1) https://doi.org/10.1186/s40494-020-00388-x
    37. Lambert Baij, Jesse Buijs, Joen J. Hermans, Laura Raven, Piet D. Iedema, Katrien Keune, Joris Sprakel. Quantifying solvent action in oil paint using portable laser speckle imaging. Scientific Reports 2020, 10 (1) https://doi.org/10.1038/s41598-020-67115-1
    38. Lucia Noor Melita, Katarzyna Węgłowska, Diego Tamburini, Capucine Korenberg. Investigating the Potential of the Er:YAG Laser for the Removal of Cemented Dust from Limestone and Painted Plaster. Coatings 2020, 10 (11) , 1099. https://doi.org/10.3390/coatings10111099
    39. Mariana B. Buscaglia, Emilia B. Halac, María Reinoso, Fernando Marte. The palette of Pio Collivadino (1869–1945) throughout his career. Journal of Cultural Heritage 2020, 44 , 27-37. https://doi.org/10.1016/j.culher.2020.02.012
    40. Koen Janssens, Marine Cotte. Using Synchrotron Radiation for Characterization of Cultural Heritage Materials. 2020, 2457-2483. https://doi.org/10.1007/978-3-030-23201-6_78
    41. Francesco Caruso, Sara Mantellato, Noëlle L. W. Streeton, Tine Frøysaker. Unveiling Harriet Backer: ICP–OES study for the characterisation of the colour tubes from her original paint box. Heritage Science 2019, 7 (1) https://doi.org/10.1186/s40494-018-0244-8
    42. Muriel Geldof, Inez Dorothé van der Werf, Ralph Haswell. The examination of Van Gogh’s chrome yellow pigments in ‘Field with Irises near Arles’ using quantitative SEM–WDX. Heritage Science 2019, 7 (1) https://doi.org/10.1186/s40494-019-0341-3
    43. Marine Wojcieszak, Lyn Wadley, Linda Prinsloo. Was yellow lead chromate pigment used during Middle Stone Age at Sibudu rock shelter (South Africa)?. Journal of Raman Spectroscopy 2019, 50 (11) , 1712-1721. https://doi.org/10.1002/jrs.5704
    44. M. Barberio, E. Skantzakis, S. Sorieul, P. Antici. Pigment darkening as case study of In-Air Plasma-Induced Luminescence. Science Advances 2019, 5 (6) https://doi.org/10.1126/sciadv.aar6228
    45. Soomin Jo, Soo Ryeon Ryu, Wonhyeong Jang, Oh-Sun Kwon, Boa Rhee, Young Eun Lee, Dongmin Kim, Jungsik Kim, Kwanwoo Shin. LED illumination-induced fading of traditional Korean pigments. Journal of Cultural Heritage 2019, 37 , 129-136. https://doi.org/10.1016/j.culher.2018.11.005
    46. Koen Janssens, Marine Cotte. Using Synchrotron Radiation for Characterization of Cultural Heritage Materials. 2019, 1-27. https://doi.org/10.1007/978-3-319-04507-8_78-1
    47. Muriel Geldof, Art Ness Proaño Gaibor, Frank Ligterink, Ella Hendriks, Eric Kirchner. Reconstructing Van Gogh’s palette to determine the optical characteristics of his paints. Heritage Science 2018, 6 (1) https://doi.org/10.1186/s40494-018-0181-6
    48. Pyeong-Koo Lee, Hye Jung Chang, Soonyoung Yu, Keun Hwa Chae, Jee-Hwan Bae, Min-Ju Kang, Gitak Chae. Characterization of Cr (VI) – Containing solid phase particles in dry dust deposition in Daejeon, South Korea. Environmental Pollution 2018, 243 , 1637-1647. https://doi.org/10.1016/j.envpol.2018.09.127
    49. M. Vagnini, R. Vivani, E. Viscuso, M. Favazza, B.G. Brunetti, A. Sgamellotti, C. Miliani. Investigation on the process of lead white blackening by Raman spectroscopy, XRD and other methods: Study of Cimabue’s paintings in Assisi. Vibrational Spectroscopy 2018, 98 , 41-49. https://doi.org/10.1016/j.vibspec.2018.07.006
    50. Costanza Miliani, Letizia Monico, Maria J. Melo, Simona Fantacci, Eva M. Angelin, Aldo Romani, Koen Janssens. Photochemistry of Artists’ Dyes and Pigments: Towards Better Understanding and Prevention of Colour Change in Works of Art. Angewandte Chemie International Edition 2018, 57 (25) , 7324-7334. https://doi.org/10.1002/anie.201802801
    51. Frederik Vanmeert, Ella Hendriks, Geert Van der Snickt, Letizia Monico, Joris Dik, Koen Janssens. Chemical Mapping by Macroscopic X‐ray Powder Diffraction (MA‐XRPD) of Van Gogh's Sunflowers : Identification of Areas with Higher Degradation Risk. Angewandte Chemie International Edition 2018, 57 (25) , 7418-7422. https://doi.org/10.1002/anie.201713293
    52. Costanza Miliani, Letizia Monico, Maria J. Melo, Simona Fantacci, Eva M. Angelin, Aldo Romani, Koen Janssens. Zur Photochemie von Künstlerfarben: Strategien zur Verhinderung von Farbveränderungen in Kunstwerken. Angewandte Chemie 2018, 130 (25) , 7447-7457. https://doi.org/10.1002/ange.201802801
    53. Frederik Vanmeert, Ella Hendriks, Geert Van der Snickt, Letizia Monico, Joris Dik, Koen Janssens. Chemical Mapping by Macroscopic X‐ray Powder Diffraction (MA‐XRPD) of Van Gogh's Sunflowers : Identification of Areas with Higher Degradation Risk. Angewandte Chemie 2018, 130 (25) , 7540-7544. https://doi.org/10.1002/ange.201713293
    54. Eric Kirchner, Ivo van der Lans, Frank Ligterink, Muriel Geldof, Luc Megens, Teio Meedendorp, Kathrin Pilz, Ella Hendriks. Digitally reconstructing Van Gogh's Field with Irises near Arles part 3: Determining the original colors. Color Research & Application 2018, 43 (3) , 311-327. https://doi.org/10.1002/col.22197
    55. Eric Kirchner, Ivo van der Lans, Frank Ligterink, Muriel Geldof, Art Ness Proano Gaibor, Ella Hendriks, Koen Janssens, John Delaney. Digitally reconstructing Van Gogh's Field with Irises near Arles. Part 2: Pigment concentration maps. Color Research & Application 2018, 43 (2) , 158-176. https://doi.org/10.1002/col.22164
    56. Ling Lee, Chih-Yuan Hsu, Hong-Wei Yen. The effects of hydraulic retention time (HRT) on chromium(VI) reduction using autotrophic cultivation of Chlorella vulgaris. Bioprocess and Biosystems Engineering 2017, 40 (12) , 1725-1731. https://doi.org/10.1007/s00449-017-1827-6
    57. Daniela Comelli, Alessia Artesani, Austin Nevin, Sara Mosca, Victor Gonzalez, Myriam Eveno, Gianluca Valentini. Time-Resolved Photoluminescence Microscopy for the Analysis of Semiconductor-Based Paint Layers. Materials 2017, 10 (11) , 1335. https://doi.org/10.3390/ma10111335
    58. ANDREA CAVICCHIOLI, PRISCILA LEITÃO DENARDI ALEGRE, ARIEL GUILGER SIMÕES MARTINS. Microambientes e conservação preventiva em áreas indoor: o caso do espaço interior não climatizado da Casa de Dona Yayá, em São Paulo (Brasil). Anais do Museu Paulista: História e Cultura Material 2017, 25 (3) , 291-340. https://doi.org/10.1590/1982-02672017v25n0309
    59. Karen Trentelman. Analyzing the Heterogeneous Hierarchy of Cultural Heritage Materials: Analytical Imaging. Annual Review of Analytical Chemistry 2017, 10 (1) , 247-270. https://doi.org/10.1146/annurev-anchem-071015-041500
    60. Jeffrey E. Fieberg, Per Knutås, Kurt Hostettler, Gregory D. Smith. “Paintings Fade Like Flowers”: Pigment Analysis and Digital Reconstruction of a Faded Pink Lake Pigment in Vincent van Gogh’s Undergrowth with Two Figures. Applied Spectroscopy 2017, 71 (5) , 794-808. https://doi.org/10.1177/0003702816685097
    61. Vanessa Otero, Joana V. Pinto, Leslie Carlyle, Márcia Vilarigues, Marine Cotte, Maria João Melo. Nineteenth century chrome yellow and chrome deep from Winsor & Newton TM. Studies in Conservation 2017, 62 (3) , 123-149. https://doi.org/10.1080/00393630.2015.1131478
    62. Diogo Sanches, Ana Maria Ramos, Jorge F.J. Coelho, Cátia S.M.F. Costa, Márcia Vilarigues, Maria João Melo. Correlating thermophysical properties with the molecular composition of 19th century chrome yellow oil paints. Polymer Degradation and Stability 2017, 138 , 201-211. https://doi.org/10.1016/j.polymdegradstab.2017.02.010
    63. M. Vagnini, F. Gabrieli, A. Daveri, D. Sali. Handheld new technology Raman and portable FT-IR spectrometers as complementary tools for the in situ identification of organic materials in modern art. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2017, 176 , 174-182. https://doi.org/10.1016/j.saa.2017.01.006
    64. Tanil Akyuz, Sevim Akyuz. Investigations on Empire series postage stamps of Ottomans (printed 1880–1890) by vibrational spectroscopic and energy dispersive X-ray fluorescence techniques. Vibrational Spectroscopy 2017, 89 , 37-43. https://doi.org/10.1016/j.vibspec.2016.12.012
    65. Shahid Sultan, Khalida Kareem, Ling He, Stefan Simon. Identification of the authenticity of pigments in ancient polychromed artworks of China. Analytical Methods 2017, 9 (5) , 814-825. https://doi.org/10.1039/C6AY03157A
    66. Marine Cotte, Emeline Pouyet, Murielle Salomé, Camille Rivard, Wout De Nolf, Hiram Castillo-Michel, Tiphaine Fabris, Letizia Monico, Koen Janssens, Tian Wang, Philippe Sciau, Louisiane Verger, Laurent Cormier, Olivier Dargaud, Emmanuel Brun, David Bugnazet, Barbara Fayard, Bernhard Hesse, Ana Elena Pradas del Real, Giulia Veronesi, Juliette Langlois, Nathalie Balcar, Yannick Vandenberghe, Vicente Armando Solé, Jérôme Kieffer, Ray Barrett, Cédric Cohen, Claude Cornu, Robert Baker, Eric Gagliardini, Emmanuel Papillon, Jean Susini. The ID21 X-ray and infrared microscopy beamline at the ESRF: status and recent applications to artistic materials. Journal of Analytical Atomic Spectrometry 2017, 32 (3) , 477-493. https://doi.org/10.1039/C6JA00356G
    67. Koen Janssens, Geert Van der Snickt, Frederik Vanmeert, Stijn Legrand, Gert Nuyts, Matthias Alfeld, Letizia Monico, Willemien Anaf, Wout De Nolf, Marc Vermeulen, Jo Verbeeck, Karolien De Wael. Non-Invasive and Non-Destructive Examination of Artistic Pigments, Paints, and Paintings by Means of X-Ray Methods. Topics in Current Chemistry 2016, 374 (6) https://doi.org/10.1007/s41061-016-0079-2
    68. Kazuhiko Nakano, Atsushi Tabe, Susumu Shimoyama, Kouichi Tsuji. Visualizing a black cat drawing hidden inside the painting by confocal micro-XRF analysis. Microchemical Journal 2016, 126 , 496-500. https://doi.org/10.1016/j.microc.2016.01.007
    69. J. Schanda, P. Csuti, F. Szabó. A New Concept of Color Fidelity for Museum Lighting. LEUKOS 2016, 12 (1-2) , 71-77. https://doi.org/10.1080/15502724.2014.978503
    70. Thiago S. Puglieri, Ariane S. Lavezzo, Isabela F.S. dos Santos, Dalva L.A. de Faria. Investigation on the hazing of a Brazilian contemporary painting. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2016, 159 , 117-122. https://doi.org/10.1016/j.saa.2016.01.035
    71. Veronika Košařová, David Hradil, Janka Hradilová, Zdeňka Čermáková, Ivan Němec, Manfred Schreiner. The efficiency of micro-Raman spectroscopy in the analysis of complicated mixtures in modern paints: Munch's and Kupka's paintings under study. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2016, 156 , 36-46. https://doi.org/10.1016/j.saa.2015.11.027
    72. B. Brunetti, C. Miliani, F. Rosi, B. Doherty, L. Monico, A. Romani, A. Sgamellotti. Non-invasive Investigations of Paintings by Portable Instrumentation: The MOLAB Experience. Topics in Current Chemistry 2016, 374 (1) https://doi.org/10.1007/s41061-015-0008-9
    73. Letizia Monico, Koen Janssens, Marine Cotte, Lorenzo Sorace, Frederik Vanmeert, Brunetto Giovanni Brunetti, Costanza Miliani. Chromium speciation methods and infrared spectroscopy for studying the chemical reactivity of lead chromate-based pigments in oil medium. Microchemical Journal 2016, 124 , 272-282. https://doi.org/10.1016/j.microc.2015.08.028
    74. Ana B. Muñoz-García, Arianna Massaro, Michele Pavone. Ab initio study of PbCr (1−x) S x O 4 solid solution: an inside look at Van Gogh Yellow degradation. Chemical Science 2016, 7 (7) , 4197-4203. https://doi.org/10.1039/C5SC04362J
    75. Anna Amat, Costanza Miliani, Simona Fantacci. Structural and electronic properties of the PbCrO 4 chrome yellow pigment and of its light sensitive sulfate-substituted compounds. RSC Advances 2016, 6 (43) , 36336-36344. https://doi.org/10.1039/C6RA01444E
    76. Letizia Monico, Koen Janssens, Ella Hendriks, Frederik Vanmeert, Geert Van der Snickt, Marine Cotte, Gerald Falkenberg, Brunetto Giovanni Brunetti, Costanza Miliani. Evidence for Degradation of the Chrome Yellows in Van Gogh’s Sunflowers : A Study Using Noninvasive In Situ Methods and Synchrotron‐Radiation‐Based X‐ray Techniques. Angewandte Chemie 2015, 127 (47) , 14129-14133. https://doi.org/10.1002/ange.201505840
    77. Letizia Monico, Koen Janssens, Ella Hendriks, Frederik Vanmeert, Geert Van der Snickt, Marine Cotte, Gerald Falkenberg, Brunetto Giovanni Brunetti, Costanza Miliani. Evidence for Degradation of the Chrome Yellows in Van Gogh’s Sunflowers : A Study Using Noninvasive In Situ Methods and Synchrotron‐Radiation‐Based X‐ray Techniques. Angewandte Chemie International Edition 2015, 54 (47) , 13923-13927. https://doi.org/10.1002/anie.201505840
    78. E. Pouyet, M. Cotte, B. Fayard, M. Salomé, F. Meirer, A. Mehta, E. S. Uffelman, A. Hull, F. Vanmeert, J. Kieffer, M. Burghammer, K. Janssens, F. Sette, J. Mass. 2D X-ray and FTIR micro-analysis of the degradation of cadmium yellow pigment in paintings of Henri Matisse. Applied Physics A 2015, 121 (3) , 967-980. https://doi.org/10.1007/s00339-015-9239-4
    79. Ingalill Nyström. Spectroscopic analysis of artists’ pigments and materials used in southern Swedish painted wall hangings from the eighteenth and nineteenth centuries. Studies in Conservation 2015, 60 (6) , 353-367. https://doi.org/10.1179/2047058414Y.0000000131
    80. Zhan Shu, Lisa Axe, Kauser Jahan, Kandalam V. Ramanujachary, Carl Kochersberger. Metal concentrations and distribution in paint waste generated during bridge rehabilitation in New York State. Science of The Total Environment 2015, 526 , 262-270. https://doi.org/10.1016/j.scitotenv.2015.03.144
    81. T. Tripković, C. Charvy, S. Alves, A.Ð. Lolić, R.M. Baošić, S.D. Nikolić-Mandić, J.C. Tabet. Electrospray Ionization Linear Trap Quadrupole Orbitrap in Analysis of Old Tempera Paintings: Application to Nineteenth-Century Orthodox Icons. European Journal of Mass Spectrometry 2015, 21 (4) , 679-692. https://doi.org/10.1255/ejms.1346
    82. Francesca Caterina Izzo, Valentina Capogrosso, Michele Gironda, Roberto Alberti, Chiara Mazzei, Luca Nodari, Arianna Gambirasi, Elisabetta Zendri, Austin Nevin. Multi‐analytical non‐invasive study of modern yellow paints from postwar Italian paintings from the International Gallery of Modern Art Cà Pesaro, Venice. X-Ray Spectrometry 2015, 44 (4) , 296-304. https://doi.org/10.1002/xrs.2623
    83. A. Rafalska-Łasocha, M. Grzesiak-Nowak, D. Sarkowicz, W. Łasocha. The use of XRPD for the investigation of historic pigments and painting materials in works by Henryk Siemiradzki. Journal of Analytical Atomic Spectrometry 2015, 30 (3) , 751-758. https://doi.org/10.1039/C4JA00341A
    84. V. Capogrosso, F. Gabrieli, S. Bellei, L. Cartechini, A. Cesaratto, N. Trcera, F. Rosi, G. Valentini, D. Comelli, A. Nevin. An integrated approach based on micro-mapping analytical techniques for the detection of impurities in historical Zn-based white pigments. Journal of Analytical Atomic Spectrometry 2015, 30 (3) , 828-838. https://doi.org/10.1039/C4JA00385C
    85. Letizia Monico, Koen Janssens, Matthias Alfeld, Marine Cotte, Frederik Vanmeert, Chris G. Ryan, Gerald Falkenberg, Daryl L. Howard, Brunetto Giovanni Brunetti, Costanza Miliani. Full spectral XANES imaging using the Maia detector array as a new tool for the study of the alteration process of chrome yellow pigments in paintings by Vincent van Gogh. Journal of Analytical Atomic Spectrometry 2015, 30 (3) , 613-626. https://doi.org/10.1039/C4JA00419A
    86. Letizia Monico, Koen Janssens, Marine Cotte, Aldo Romani, Lorenzo Sorace, Chiara Grazia, Brunetto Giovanni Brunetti, Costanza Miliani. Synchrotron-based X-ray spectromicroscopy and electron paramagnetic resonance spectroscopy to investigate the redox properties of lead chromate pigments under the effect of visible light. Journal of Analytical Atomic Spectrometry 2015, 30 (7) , 1500-1510. https://doi.org/10.1039/C5JA00091B
    87. Jwo‐Huei Jou, Kun‐Yi Chou, Fu‐Chin Yang, Ching‐Heng Hsieh, Sudhir Kumar, Abhishek Agrawal, Sun‐Zen Chen, Tsung‐Han Li, Hui‐Huan Yu. Pseudo‐natural Light for Displays and Lighting. Advanced Optical Materials 2015, 3 (1) , 95-102. https://doi.org/10.1002/adom.201400366
    88. Tanja Špec, Klara Retko, Polonca Ropret, Anton Meden, Janez Bernard. The influence of UV–Vis radiation, and oscillations of temperature and relative humidity, on malachite alteration in the presence of different organic binders and varnishes. Journal of Raman Spectroscopy 2014, 45 (11-12) , 1068-1075. https://doi.org/10.1002/jrs.4518
    89. Letizia Monico, Koen Janssens, Ella Hendriks, Brunetto G. Brunetti, Costanza Miliani. Raman study of different crystalline forms of PbCrO 4 and PbCr 1−x S x O 4 solid solutions for the noninvasive identification of chrome yellows in paintings: a focus on works by Vincent van Gogh. Journal of Raman Spectroscopy 2014, 45 (11-12) , 1034-1045. https://doi.org/10.1002/jrs.4548
    90. Eva Grieten, Joost Caen, Dominique Schryvers. Optimal Sample Preparation to Characterize Corrosion in Historical Photographs with Analytical TEM. Microscopy and Microanalysis 2014, 20 (5) , 1585-1590. https://doi.org/10.1017/S1431927614012860
    91. Leili Aghebati-maleki, Bahareh Salehi, Rezvan Behfar, Hajar Saeidmanesh, Fereshte Ahmadian, Mohammadtaghi Sarebanhassanabadi, Masoud Negahdary. Designing a Hydrogen Peroxide Biosensor Using Catalase and Modified Electrode with Magnesium Oxide Nanoparticles. International Journal of Electrochemical Science 2014, 9 (1) , 257-271. https://doi.org/10.1016/S1452-3981(23)07714-3
    92. Haiyan Tan, He Tian, Jo Verbeeck, Letizia Monico, Koen Janssens, Gustaaf Van Tendeloo. Nanoscale Investigation of the Degradation Mechanism of a Historical Chrome Yellow Paint by Quantitative Electron Energy Loss spectroscopy Mapping of Chromium Species. Angewandte Chemie International Edition 2013, 52 (43) , 11360-11363. https://doi.org/10.1002/anie.201305753
    93. Haiyan Tan, He Tian, Jo Verbeeck, Letizia Monico, Koen Janssens, Gustaaf Van Tendeloo. Nanoscale Investigation of the Degradation Mechanism of a Historical Chrome Yellow Paint by Quantitative Electron Energy Loss spectroscopy Mapping of Chromium Species. Angewandte Chemie 2013, 125 (43) , 11570-11573. https://doi.org/10.1002/ange.201305753
    94. Matthias Alfeld, José A.C. Broekaert. Mobile depth profiling and sub-surface imaging techniques for historical paintings—A review. Spectrochimica Acta Part B: Atomic Spectroscopy 2013, 88 , 211-230. https://doi.org/10.1016/j.sab.2013.07.009
    95. Koen Janssens, Matthias Alfeld, Geert Van der Snickt, Wout De Nolf, Frederik Vanmeert, Marie Radepont, Letizia Monico, Joris Dik, Marine Cotte, Gerald Falkenberg, Costanza Miliani, Brunetto G. Brunetti. The Use of Synchrotron Radiation for the Characterization of Artists' Pigments and Paintings. Annual Review of Analytical Chemistry 2013, 6 (1) , 399-425. https://doi.org/10.1146/annurev-anchem-062012-092702
    96. Marine Cotte. Application des méthodes synchrotron au domaine du patrimoine culturel. Reflets de la physique 2013, (34-35) , 98-100. https://doi.org/10.1051/refdp/201334098
    97. Erich S. Uffelman, Patricia A. Hobbs, Derek A. G. Barisas, Jennifer L. Mass. pXRF analyses of Louise Herreshoff’s paintings in relation to CdS and other pigment degradation issues. Applied Physics A 2013, 111 (1) , 9-14. https://doi.org/10.1007/s00339-012-7528-8
    98. Francesca Casadio, Volker Rose. High-resolution fluorescence mapping of impurities in historical zinc oxide pigments: hard X-ray nanoprobe applications to the paints of Pablo Picasso. Applied Physics A 2013, 111 (1) , 1-8. https://doi.org/10.1007/s00339-012-7534-x
    99. M. Oujja, M. Sanz, E. Rebollar, J.F. Marco, C. Domingo, P. Pouli, S. Kogou, C. Fotakis, M. Castillejo. Wavelength and pulse duration effects on laser induced changes on raw pigments used in paintings. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2013, 102 , 7-14. https://doi.org/10.1016/j.saa.2012.10.001
    100. Jennifer Mass, Julia Sedlmair, Catherine Schmidt Patterson, David Carson, Barbara Buckley, Carol Hirschmugl. SR-FTIR imaging of the altered cadmium sulfide yellow paints in Henri Matisse's Le Bonheur de vivre (1905–6) – examination of visually distinct degradation regions. The Analyst 2013, 138 (20) , 6032. https://doi.org/10.1039/c3an00892d
    Load all citations
    Download PDF

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    You’ve supercharged your research process with ACS and Mendeley!

    STEP 1:
    Click to create an ACS ID

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    MENDELEY PAIRING EXPIRED
    Your Mendeley pairing has expired. Please reconnect