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Natural (Mg,Fe)SiO3-Ilmenite and -Perovskite in the Tenham Meteorite

Science
22 Aug 1997
Vol 277, Issue 5329
pp. 1084-1086

Abstract

The minerals (Mg,Fe)SiO3-ilmenite and -perovskite were identified in the shock-induced veins in the Tenham chondritic meteorite. Both phases are inferred to have transformed from pyroxene at high pressures and temperatures by shock metamorphism. Columnar-shaped ilmenite grains, one of two types of morphologies, have a topotaxial relationship with neighboring pyroxene grains, indicating shear transformation. Granular-shaped perovskite grains showed a diffraction pattern consistent with orthorhombic perovskite, but these grains were not stable under the electron beam irradiation and became amorphous. The higher iron concentration in both phases compared with those experimentally reported may suggest their metastable transition from enstatite because of shock compression.

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Extrapolated lattice parameters of (Mg1–x,Fex)SiO3-ilmenite and -perovskite with x = 0.2 from those of the synthetic samples are a = 0.473 and c = 1.359 nm (c/a = 2.873) and a = 0.480 and c = 0.691 nm, respectively. Data of synthetic samples were taken from E. Ito and H. Yamada [in High-Pressure Research in Geophysics, S. Akimoto and M. H. Manghnani, Eds. (Center for Academic Publications, Tokyo, 1982), pp. 405–419] and Y. Fei, Y. Wang, and L. W. Finger [J. Geophys. Res. 101, 11525 (1996)]. Taking the accuracy of the lattice parameters from the SAED pattern into account, they agree well with the extrapolated values, and still rule out the possibilities of any other polymorph of (Mg,Fe)SiO3.
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We thank Y. Syono and N. Miyajima for helpful comments and T. Kuwajima and R. Tanaka for technical assistance. Supported by a Grant-in-Aid for Research (no. 06402019) from the Ministry of Education, Science, and Culture of the Japanese Government.

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Published In

Science
Volume 277 | Issue 5329
22 August 1997

Submission history

Received: 15 April 1997
Accepted: 11 July 1997
Published in print: 22 August 1997

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Authors

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Naotaka Tomioka*
Division of Earth and Planetary Sciences, Graduate School of Science, Hokkaido University, Sapporo 060, Japan.
Kiyoshi Fujino
Division of Earth and Planetary Sciences, Graduate School of Science, Hokkaido University, Sapporo 060, Japan.

Notes

*
To whom correspondence should be addressed. E-mail: [email protected]

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