Controlled Crystal Growth of Two-Dimensional Layered Nanomaterials in Hydrogel via a Modified Electrical Double Migration Method
- Gyeong-Hyeon Gwak
- ,
- Na Kyung Kwon
- ,
- Won-Jae Lee
- ,
- Seung-Min Paek
- ,
- So Youn Kim
- , and
- Jae-Min Oh
Abstract
Layered double hydroxide (LDH) nanomaterials of uniform size and homogeneous distribution are successfully developed in agarose hydrogel through the electrical double migration method. To grow LDH crystals in agarose matrix, both cationic (Ni2+, Ga3+) and anionic precursors (OH– and CO32–) of LDH are simultaneously transported from solution to agarose hydrogel through electric potential, resulting in the in situ crystal growth of LDH. X-ray diffraction patterns, X-ray absorption spectra, and high-resolution transmission electron microscopic images confirm that the developed LDH is ∼15 nm in size and had a well-defined crystal structure. Scanning electron microscopy and small-angle X-ray scattering spectroscopy showed homogeneous arrays of LDH nanocrystals along agarose sheets with homogeneous distribution. On the basis of the characterization results, we suggest that crystal nuclei are first developed on the agarose chain, and then LDHs homogeneously grow along sheets of agarose matrix.
Cited By
This article is cited by 2 publications.
- Yasuaki Tokudome, Vanessa Prevot, Naoki Tarutani. Processing porous architectures based on LDH: Synthesis and novel applications. Applied Clay Science 2023, 243 , 107051. https://doi.org/10.1016/j.clay.2023.107051
- Toshiyuki Hibino. Deterioration of anion-adsorption abilities of layered double hydroxides synthesized in agarose gel. Applied Clay Science 2020, 186 , 105435. https://doi.org/10.1016/j.clay.2019.105435