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Multilayers of Fluorinated Amphiphilic Polyions for Marine Fouling Prevention

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† Institute of Materials Research and Engineering A*STAR (Agency for Science, Technology and Research), 3 Research Link Singapore 117602
‡ Tropical Marine Science Institute, National University of Singapore, 18 Kent Ridge Road Singapore 119227
§ Institute of Chemical and Engineering Sciences A*STAR, 1, Pesek Road, Jurong Island, Singapore627833
∥ MESA+ Institute for Nanotechnology, Materials Science and Technology of Polymers, University of Twente, P.O. Box 217, 7500 AE Enschede, The Netherlands
*Tel: +65 6874 5443; Fax: +65 6872 0785; E-mail: [email protected] (D.J.).
*Tel: +31 53 489 2974; Fax: +31 53 489 3823; E-mail: [email protected] (G.J.V.).
Cite this: Langmuir 2014, 30, 1, 288–296
Publication Date (Web):December 11, 2013
https://doi.org/10.1021/la404300r
Copyright © 2013 American Chemical Society
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    Abstract

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    Sequential layer-by-layer (LbL) deposition of polyelectrolytes followed by chemical cross-linking was investigated as a method to fabricate functional amphiphilic surfaces for marine biofouling prevention applications. A novel polyanion, grafted with amphiphilic perfluoroalkyl polyethylene glycol (fPEG) side chains, was synthesized and subsequently used to introduce amphiphilic character to the LbL film. The structure of the polyanion was confirmed by FTIR and NMR. Amphiphilicity of the film assembly was demonstrated by both water and hexadecane static contact angles. XPS studies of the cross-linked and annealed amphiphilic LbL films revealed the increased concentration of fPEG content at the film interface. In antifouling assays, the amphiphilic LbL films effectively prevented the adhesion of the marine bacterium Pseudomonas (NCIMB 2021).

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