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Photoreduction of Graphene Oxide and Photochemical Synthesis of Graphene–Metal Nanoparticle Hybrids by Ketyl Radicals

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† †Department of Macromolecular Science and Engineering, ‡Department of Radiology, and §Department of Chemistry, Case Western Reserve University, Cleveland, Ohio 44106 United States
⊥ Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37830, United States
*E-mail: [email protected]. Tel.: 216-368-4566.
Cite this: ACS Appl. Mater. Interfaces 2017, 9, 29, 24887–24898
Publication Date (Web):July 5, 2017
https://doi.org/10.1021/acsami.7b06275
Copyright © 2017 American Chemical Society
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    Abstract

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    The photoreduction of graphene oxide (GO) using ketyl radicals is demonstrated for the first time. The use of photochemical reduction through ketyl radicals generated by I-2959 or (1-[4-(2-hydroxyethoxy)phenyl]-2-hydroxy-2-methyl-1-propan-1-one) is interesting because it affords spatial and temporal control of the reduction process. Graphene–metal nanoparticle hybrids of Ag, Au, and Pd were also photochemically fabricated in a one-pot procedure. Comprehensive spectroscopic and imaging techniques were carried out to fully characterize the materials. The nanoparticle hybrids showed promising action for the catalytic degradation of model environmental pollutants, namely, 4-nitrophenol, Rose Bengal, and Methyl Orange. The process described can be extended to polymer nanocomposites that can be photopatterned and could be potentially extended to fabricating plastic electronic devices.

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acsami.7b06275.

    • Detailed high-resolution XPS studies, Raman spectra on SERS effect of metal nanoparticle, standard bright-field TEM micrographs of the GO–metal nanoparticle hybrids and TEM-EDX mapping of rGO–AuNP, detailed data on the catalytic degradation of the three model environmental pollutants, and photopatterning (PDF)

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